Chinese Journal of Organic Chemistry ›› 2024, Vol. 44 ›› Issue (3): 951-965.DOI: 10.6023/cjoc202312005 Previous Articles Next Articles
ARTICLES
韩璐瑶a, 胡硕真a, 郭庆春b, 郭红永b, 高照群a, 许颖a, 张新胜a,*()
收稿日期:
2023-12-06
修回日期:
2024-02-23
发布日期:
2024-04-02
Luyao Hana, Shuozhen Hua, Qingchun Guob, Hongyong Guob, Zhaoqun Gaoa, Ying Xua, Xinsheng Zhanga()
Received:
2023-12-06
Revised:
2024-02-23
Published:
2024-04-02
Contact:
*E-mail: xszhang@ecust.edu.cn
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Luyao Han, Shuozhen Hu, Qingchun Guo, Hongyong Guo, Zhaoqun Gao, Ying Xu, Xinsheng Zhang. Study on Electrooxidation of Benzophenone Hydrazone to Diphenyldiazomethane[J]. Chinese Journal of Organic Chemistry, 2024, 44(3): 951-965.
Entry | Electrolyte | Conv.b/% | Yield/% | |||
---|---|---|---|---|---|---|
1c | 2d | 3e | 4f | |||
1 | (NH4)2CO3 | 49.4 | 39.5 | 4.8 | 0 | <0.1 |
2 | NH4HCO3 | 54.0 | 36.3 | 5.1 | <0.1 | 2.3 |
3 | CH3COONH4 | 47.4 | 18.2 | 10.7 | 2.8 | 2.9 |
4 | (NH4)2HPO4 | 67.2 | 8.8 | 29.0 | 3.8 | 0.1 |
Entry | Electrolyte | Conv.b/% | Yield/% | |||
---|---|---|---|---|---|---|
1c | 2d | 3e | 4f | |||
1 | (NH4)2CO3 | 49.4 | 39.5 | 4.8 | 0 | <0.1 |
2 | NH4HCO3 | 54.0 | 36.3 | 5.1 | <0.1 | 2.3 |
3 | CH3COONH4 | 47.4 | 18.2 | 10.7 | 2.8 | 2.9 |
4 | (NH4)2HPO4 | 67.2 | 8.8 | 29.0 | 3.8 | 0.1 |
Entry | Solvent type | Dipole moment/(×10-30 C•m) | Conv.b/% | Yield/% | |||
---|---|---|---|---|---|---|---|
1 c | 2d | 3e | 4f | ||||
1 | DMSO | 13.34 | 100.0 | 34.7 | 43.3 | 16.7 | 1.7 |
2 | DMF | 12.88 | 100.0 | 66.3 | 16.3 | 6.6 | 1.0 |
3 | DMAc | 12.41 | 99.4 | 73.8 | 3.3 | 3.1 | 1.6 |
4 | ACN | 11.47 | 73.2 | 41.3 | 3.8 | 0.8 | 10.0 |
Entry | Solvent type | Dipole moment/(×10-30 C•m) | Conv.b/% | Yield/% | |||
---|---|---|---|---|---|---|---|
1 c | 2d | 3e | 4f | ||||
1 | DMSO | 13.34 | 100.0 | 34.7 | 43.3 | 16.7 | 1.7 |
2 | DMF | 12.88 | 100.0 | 66.3 | 16.3 | 6.6 | 1.0 |
3 | DMAc | 12.41 | 99.4 | 73.8 | 3.3 | 3.1 | 1.6 |
4 | ACN | 11.47 | 73.2 | 41.3 | 3.8 | 0.8 | 10.0 |
Entry | Amplification coefficient | Conv.d/% | Current efficiency/% | Yielde/% | |||
---|---|---|---|---|---|---|---|
1 | 2 | 3 | 4 | ||||
1a | 1 | 100.0 | 58.9 | 73.7 | 7.6 | 2.9 | 1.2 |
2b | 5 | 99.9 | 57.9 | 72.4 | 7.3 | 2.5 | 0.2 |
3c | 10 | 100.0 | 56.4 | 70.5 | 7.8 | 2.1 | 0.4 |
Entry | Amplification coefficient | Conv.d/% | Current efficiency/% | Yielde/% | |||
---|---|---|---|---|---|---|---|
1 | 2 | 3 | 4 | ||||
1a | 1 | 100.0 | 58.9 | 73.7 | 7.6 | 2.9 | 1.2 |
2b | 5 | 99.9 | 57.9 | 72.4 | 7.3 | 2.5 | 0.2 |
3c | 10 | 100.0 | 56.4 | 70.5 | 7.8 | 2.1 | 0.4 |
Entry | c(BPH)/(mol•L-1) | Conv.b/% | Current efficiency/% | Yield/% | |||
---|---|---|---|---|---|---|---|
1 c | 2d | 3e | 4f | ||||
1 | 0.0975 | 100.0 | 58.9 | 73.7 | 7.6 | 2.9 | 1.2 |
2 | 0.1951 | 100.0 | 50.8 | 63.4 | 7.4 | 4.1 | 1.4 |
3 | 0.4878 | 95.9 | 41.2 | 51.4 | 1.8 | 2.5 | 1.8 |
4 | 0.9756 | 91.4 | 39.6 | 49.5 | 0.7 | 1.7 | 2.2 |
Entry | c(BPH)/(mol•L-1) | Conv.b/% | Current efficiency/% | Yield/% | |||
---|---|---|---|---|---|---|---|
1 c | 2d | 3e | 4f | ||||
1 | 0.0975 | 100.0 | 58.9 | 73.7 | 7.6 | 2.9 | 1.2 |
2 | 0.1951 | 100.0 | 50.8 | 63.4 | 7.4 | 4.1 | 1.4 |
3 | 0.4878 | 95.9 | 41.2 | 51.4 | 1.8 | 2.5 | 1.8 |
4 | 0.9756 | 91.4 | 39.6 | 49.5 | 0.7 | 1.7 | 2.2 |
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