Chinese Journal of Organic Chemistry ›› 2024, Vol. 44 ›› Issue (3): 966-971.DOI: 10.6023/cjoc202310029 Previous Articles Next Articles
ARTICLES
陈红斌, 杨思佳, 叶智鹏, 陈凯*(), 向皞月*(), 阳华*()
收稿日期:
2023-10-30
修回日期:
2023-12-28
发布日期:
2024-04-02
作者简介:
共同第一作者
基金资助:
Hongbing Chen, Sijia Yang, Zhipeng Ye, Kai Chen(), Haoyue Xiang(), Hua Yang()
Received:
2023-10-30
Revised:
2023-12-28
Published:
2024-04-02
Contact:
*E-mail: hyangchem@csu.edu.cn; xianghaoyue@csu.edu.cn; kaichen@csu.edu.cn
About author:
These authors contributed equally to this work.
Supported by:
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Hongbing Chen, Sijia Yang, Zhipeng Ye, Kai Chen, Haoyue Xiang, Hua Yang. Electrocatalytic Reduction of Quinolines and Ketones by Using Lewis Base-Ligated Borane as a Hydrogen Donor[J]. Chinese Journal of Organic Chemistry, 2024, 44(3): 966-971.
Entry | Solvent | I/mA | LB-BH3 | +/- | T/℃ | Yield/% |
---|---|---|---|---|---|---|
1 | DMSO | 8 | LB1 | Zn/Pt | 30 | Trace |
2 | CDCl3 | 8 | LB1 | Zn/Pt | 30 | Trace |
3 | THF | 8 | LB1 | Zn/Pt | 30 | 51 |
4 | PhMe | 8 | LB1 | Zn/Pt | 30 | 30 |
5 | MeCN | 8 | LB1 | Zn/Pt | 30 | 61 |
6 | MeCN | 6 | LB1 | Zn/Pt | 30 | 53 |
7 | MeCN | 10 | LB1 | Zn/Pt | 30 | 30 |
8 | MeCN | 8 | LB2 | Zn/Pt | 30 | <50 |
9 | MeCN | 8 | LB3 | Zn/Pt | 30 | 58 |
10 | MeCN | 8 | LB4 | Zn/Pt | 30 | 70 |
11 | MeCN | 8 | LB4 | Zn/C | 30 | 50 |
12 | MeCN | 8 | LB4 | Zn/Pt | 30 | 74 |
13 | MeCN | 8 | LB4 | Zn/Cu | 30 | 58 |
14 | MeCN | 8 | LB4 | Zn/Al | 30 | 72 |
15 | MeCN | 8 | LB4 | Zn/Pt | 40 | 74 |
16 | MeCN | 8 | LB4 | Zn/Pt | 50 | 78 |
17 | MeCN | 8 | LB4 | Zn/Pt | 60 | 80 |
18b | MeCN | 8 | LB4 | Zn/Al | 50 | 82 |
19 | MeCN | 8 | — | Zn/Al | 50 | nd |
20 | MeCN | — | LB4 | Zn/Al | 50 | nd |
Entry | Solvent | I/mA | LB-BH3 | +/- | T/℃ | Yield/% |
---|---|---|---|---|---|---|
1 | DMSO | 8 | LB1 | Zn/Pt | 30 | Trace |
2 | CDCl3 | 8 | LB1 | Zn/Pt | 30 | Trace |
3 | THF | 8 | LB1 | Zn/Pt | 30 | 51 |
4 | PhMe | 8 | LB1 | Zn/Pt | 30 | 30 |
5 | MeCN | 8 | LB1 | Zn/Pt | 30 | 61 |
6 | MeCN | 6 | LB1 | Zn/Pt | 30 | 53 |
7 | MeCN | 10 | LB1 | Zn/Pt | 30 | 30 |
8 | MeCN | 8 | LB2 | Zn/Pt | 30 | <50 |
9 | MeCN | 8 | LB3 | Zn/Pt | 30 | 58 |
10 | MeCN | 8 | LB4 | Zn/Pt | 30 | 70 |
11 | MeCN | 8 | LB4 | Zn/C | 30 | 50 |
12 | MeCN | 8 | LB4 | Zn/Pt | 30 | 74 |
13 | MeCN | 8 | LB4 | Zn/Cu | 30 | 58 |
14 | MeCN | 8 | LB4 | Zn/Al | 30 | 72 |
15 | MeCN | 8 | LB4 | Zn/Pt | 40 | 74 |
16 | MeCN | 8 | LB4 | Zn/Pt | 50 | 78 |
17 | MeCN | 8 | LB4 | Zn/Pt | 60 | 80 |
18b | MeCN | 8 | LB4 | Zn/Al | 50 | 82 |
19 | MeCN | 8 | — | Zn/Al | 50 | nd |
20 | MeCN | — | LB4 | Zn/Al | 50 | nd |
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