Advances in Design of Covalent Organic Frameworks and Their Application in Catalytic C—H Activation

doi:10.6023/cjoc202410015

Abstract

Covalent organic frameworks (COFs) are emerging as significant porous materials in the field of catalysis, owing to their unique designability, high porosity, favorable crystallinity, and customizable pore environments. Recent advancements in COFs research have led to increased structural diversity and the exploration of various construction strategies, showcasing their remarkable application prospects in catalysis. This paper offers a comprehensive overview of common strategies employed in constructing COFs based on their fundamental structures. Additionally, several practical applications of COFs in C—H activation are highlighted, elucidating the catalytic mechanisms involved in these reactions. Finally, the current challenges and issues confronting COFs in the realm of catalysis are explored, intending to provide valuable guidance for their future development in C—H activation.

Key words: covalent organic frameworks (COFs), modification schemes, C—H activation

Cite this article

Xuan Wang, Maochen Liu, Yao Zhong, Renjie Song. Advances in Design of Covalent Organic Frameworks and Their Application in Catalytic C—H Activation[J]. Chinese Journal of Organic Chemistry, 2025, 45(2): 448-465.

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Fig. & Tab. 22

Figure 1. Typical structures used to build COFs

Figure 3. Typical connections in COFs

Figure 7. Synthesis of NQ-COFE5-O

Figure 8. Synthesis of COF-SH and CsPbX3@COF-SH

Figure 10. Glaser-Hay reaction catalyzed by Cu@IISERP-COF9

Figure 11. Coupling reaction between terminal acetylene and H-phosphonate catalyzed by TPT-COF-Cu

Figure 12. Carboxylation of C(sp)—H with CO2 catalyzed by TG-DMPZ

Figure 13. Synthesis of 6-substituted phenanthrene catalyzed by 2D-COF-1

Figure 14. 2D-COF-2 photocatalytic decarboxylated alkylation reaction

Figure 15. Trifluoromethylation of aromatic and heteroaromatic hydrocarbons photocatalyzed by TTO-COF

Figure 16. [4＋2] cyclization of benzene with acetylene photocatalyzed by Rh-COF-316

Figure 17. Condensation of 2-Hydroxyacetophenone with benzaldehyde catalyzed by Cu@PI-COF

Figure 18. CDC coupling reaction photocatalyzed by COF- JLU5

Figure 19. COFs composite photocatalyzed cyanidation of tertiary amines

Figure 20. Asymmetric α-benzylation of aldehydes catalyzed by chiral COFs

Figure 22. TpAQ-COF catalyze the formation of C—F bonds

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共价有机框架的设计及其在催化C—H活化领域的应用进展