Studies on the acylthiosemicarbazides and their related heterocyclic derivatives II. Synthesis of 1-[5-(\a\-naphtyl)-2H-tetrazol-2-ylacetyl]-4-phenyl thiosemicarbazide and its related heterocyclic derivatives

Chin. J. Org. Chem. ›› 1986, Vol. 6 ›› Issue (3): 184-187. Previous Articles Next Articles

酰氨基硫脲及其相关杂环衍生物的研究II.1-[5-(α-萘)-2H-四唑-2-乙酰[-4-苯基氨基硫脲及其相关环衍生物的合成

张自义;杨虎

兰州大学化学系

发布日期:1986-06-25

Studies on the acylthiosemicarbazides and their related heterocyclic derivatives II. Synthesis of 1-[5-(\a\-naphtyl)-2H-tetrazol-2-ylacetyl]-4-phenyl thiosemicarbazide and its related heterocyclic derivatives

ZHANG ZIYI;YANG HU

Published:1986-06-25

Abstract

The title compound (I) was prepared in 81% yield by the reaction of 5-(a-naphthyl)-2H-tetrazol-2-ylacetylhydrazine with PhNCS in EtOH. Cyclization reactions of I in aqueous NaOH, concentrate H2SO4 or Hg(OAc)2-EtOH gave corresponding triazole (II), thiadiazole III (X = S) and oxadiazole III (X = O) resp. I and II showed promoting effects on the growth of plumule of wheat at 1 ppm.

Key words: INFRARED SPECTROPHOTOMETRY, MASS SPECTROGRAPHY, NMR SPECTROMETRY, NITROGEN HETEROCYCLICS, NAPHTHALENE P, THIOUREAS, BENZENE P, TETRAZOLE P, AMIDO, THIOSEMICARBAZIDE P

CLC Number:

O629

Cite this article

ZHANG ZIYI;YANG HU. Studies on the acylthiosemicarbazides and their related heterocyclic derivatives II. Synthesis of 1-[5-(\a\-naphtyl)-2H-tetrazol-2-ylacetyl]-4-phenyl thiosemicarbazide and its related heterocyclic derivatives[J]. Chin. J. Org. Chem., 1986, 6(3): 184-187.

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酰氨基硫脲及其相关杂环衍生物的研究II.1-[5-(α-萘)-2H-四唑-2-乙酰[-4-苯基氨基硫脲及其相关环衍生物的合成

Studies on the acylthiosemicarbazides and their related heterocyclic derivatives II. Synthesis of 1-[5-(\a\-naphtyl)-2H-tetrazol-2-ylacetyl]-4-phenyl thiosemicarbazide and its related heterocyclic derivatives

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