Study on hydrocarboxylation of styrene using Co~2(CO)3/pyridine complex as catalyst

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Chin. J. Org. Chem. ›› 1986, Vol. 6 ›› Issue (3): 216-219. Previous Articles Next Articles

CO~2(CO)~8/吡啶络合催化苯乙烯氢羧化反应的研究

夏志高;金子林

大连工学院化学工程系

发布日期:1986-06-25

Study on hydrocarboxylation of styrene using Co~2(CO)3/pyridine complex as catalyst

XIA ZHIGAO;JIN ZILIN

Published:1986-06-25

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Abstract

The hydrocarboxylation of PhCH:CH2 with CO in MeOH under pressure catalyzed by Co2(CO)8 to give a mixture of PhCH2CH2CO2Me, MeCHPhCO2Me, and PhEt was greatly enhanced by the addition of pyridine or its alkyl-substituted derivatives The effects of temperature and pressure on the catalytic activity of pyridine were studied. The mechanism for the catalysis was discussed.

Key words: STYRENE, HOMOGENEOUS CATALYSIS, CARBONYL COMPLEX, PYRIDINE, COBALT COMPLEX, COMPLEX CATALYSIS

CLC Number:

O643

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XIA ZHIGAO;JIN ZILIN. Study on hydrocarboxylation of styrene using Co~2(CO)3/pyridine complex as catalyst[J]. Chin. J. Org. Chem., 1986, 6(3): 216-219.

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CO~2(CO)~8/吡啶络合催化苯乙烯氢羧化反应的研究

Study on hydrocarboxylation of styrene using Co~2(CO)3/pyridine complex as catalyst

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