Chin. J. Org. Chem. ›› 1987, Vol. 7 ›› Issue (3): 224-226. Previous Articles     Next Articles

聚合物试剂的研究II.应用聚合物试剂合成桃柱螟性信息素-反-10-十六碳烯-1-醛

陈家威;蒋济隆;吴银秋   

  1. 湖北大学化学系
  • 发布日期:1987-06-25

Studies on polymeric reagents II. synthesis of dichocrocis punctiferalis guenee, trans-10-hexadecene-1-al, by using polymeric reagent

CHEN JIAWEI;JIANG JILONG;WU YINQIU   

  • Published:1987-06-25

Reaction of Me(CH2)4CHO with polymer-supported Wittig reagent [-C6H5P+Ph2(CH2)10OH] Br- gave cis-10-hexadecenol (I). Isomerization of I, followed by oxidation gave trans-10-hexadecen-1-al.

Key words: C16 COMPOUNDS, GAS CHROMATOGRAPHY, WITTIG REACTION, PROTON MAGNETIC RESONANCE SPECTROMETRY, MONOALDEHYDE, STEREOCHEMISTRY, SEX PHEROMONE, HIGHER ALKENE P, PHASPHOURS-CONTAINING POLYMER, DICHOCROCIS PUNCTIFERALIS

CLC Number: