The synthesis of a porphyrin-anthraguinone-trinitrophenol triplex compound and the primary study of its fluorescence property

Abstract

This paper reports the synthesis of a porphyrin-anthraguinone-trinitrophenol triplex compound (P-AQ-T). linking 5-p-hydroxyphenyl-10, 15, 20-triphenylporphyrin and picric acid by 1,5-di(haloacetamido) anthraguinone forms P-AQ-T. comparing UV and fluorescence spectroscopy of P-AQ-T, P-AQ and TPP shows that their fluorescence guantum yields are TPP>P-AQ>P-AQ-T. this result suggests that in this triplex there exists more stsable charge separated state P+-AQ+-T=P+-AQ-T+ because of the trinitrophenol oiety as electron acceptor.

Key words: FLUORIMETRIC ANALYSIS, ULTRAVIOLET SPECTROPHOTOMETRY, PORPHYRIN, TERNARY SYSTEM, TRINITROPHENOL P, ANTHRAQUINONE P, QUANTUM YIELD, QUENCHING

CLC Number:

O651

Cite this article

ZHENG QIONG;HU TAO;LI PINGYING;HUANG SUQIU. The synthesis of a porphyrin-anthraguinone-trinitrophenol triplex compound and the primary study of its fluorescence property[J]. Chin. J. Org. Chem., 1993, 13(1): 68-72.

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