Chin. J. Org. Chem. ›› 1994, Vol. 14 ›› Issue (4): 370-375. Previous Articles     Next Articles

Original Articles

双[1,3-二(三甲硅基)环戊二烯基]四羰基二铁的反应性

孔垂华;徐善生;周秀中;王瑾玲;缪方明   

  1. 南开大学化学系;天津师范大学化学系
  • 发布日期:1994-08-25

Reactivity of bis [ 1,3-di( trimethylsilyl ) cyclopentadienyl ] tetracarbonyl di-iron

KONG CHUIHUA;XU SHANSHENG;ZHOU XIUZHONG;WANG JINLING;MIAO FANGMING   

  • Published:1994-08-25

The Fe-Fe bond of the molecule of the title compound was cleaved by sodium amalgam and gave the corresponding mononuclear iron anion. The nucleophilic reactions of the anion ith variant halides produced respectively the alkylation products on iron atom. The Fe-Fe bond of the title compound was also cleaved by halogen and HgCl~2 and resulted to form derivatives of iron halides and iron chloromecurate.

Key words: CRYSTAL STRUCTURE, REACTIVITY

CLC Number: