Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (3): 296-302. Previous Articles     Next Articles

Original Articles

烷基对蒽衍生物在水-乙腈中用硝酸铈铵氧化机理的影响

李昭昭;LAREN M. TOLBERT   

  1. 福建师范大学化学系;乔治亚理工大学化学与生化系
  • 发布日期:1995-06-25

Effect of alkyl in oxidation of alkylanthracene by ceric ammonium nitrate in water-acetonitrile

LI ZAOZAO;LAREN M. TOLBERT   

  • Published:1995-06-25

Oxidation of 9-alkylanthracene and 9,10-dialkylanthracene by ceric ammonium nitrate in water-acetonitrile proceeded oxidation, hydrolysis, oxidation , hydrolysis, elimination, oxidation and deprotonation, and obtained ring oxidative products when the alkyls were methyl, ethty and cyclopropyl. The rate of lossing of alkyl or hydrogen was H>CH~3>C~2H~5. Oxidation of aceanthracene proceeded oxidation, deprotonation, oxidation, hydrolysis and oxidation (or elimination) , and side-chain oxidation was major procedure.

Key words: OXIDATION, ANTHRACENE

CLC Number: