Synthesis of benzodioxene derivative of methylene bridged oligomer of p-nithophenol

Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (4): 403-407. Previous Articles Next Articles

Original Articles

对硝基苯酚亚甲基桥齐聚物的苯并二恶唑环衍生物的合成

孙祥玉;赵瑶兴

中国科学技术大学研究生院

发布日期:1995-08-25

Synthesis of benzodioxene derivative of methylene bridged oligomer of p-nithophenol

SUN XIANGYU;ZHAO YAOXING

Published:1995-08-25

Abstract

The reaction of bis(p-nitrophenoxy)-methane or p-nitrophenol with the excess paraformaldehyde under the pressence of concentrated sulfuric acid was investigated , and the benzodioxene derivative of methylene bridged oligomer of p-nitrophenol with two or three benzene nucoeus obtained. The four products were separated by chromatography, identified by IR, ^1H NMR, MS, respectively and three new compounds yielded. These compounds are used to Convergent stepwise synthesis of calixarene and long-chain methylene bridged oligomer.

Key words: REARRANGEMENT REACTION, ACETALIZATION

CLC Number:

O621

Cite this article

SUN XIANGYU;ZHAO YAOXING. Synthesis of benzodioxene derivative of methylene bridged oligomer of p-nithophenol[J]. Chin. J. Org. Chem., 1995, 15(4): 403-407.

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对硝基苯酚亚甲基桥齐聚物的苯并二恶唑环衍生物的合成

Synthesis of benzodioxene derivative of methylene bridged oligomer of p-nithophenol

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