Synthesis, crystal structure, transesterifications of the complex of β-  butoxycarbonylethyltin trichlorides with schiff base ligands

Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (2): 206-212. Previous Articles Next Articles

β- 丁氧酯基三氯化锡与席夫碱配合物的合成、结构与酯交换反应

李忠芳;王素文;谭小耀;傅芳信;潘华德

山东工程学院科技研究院;东北师范大学化学系.长春(130024)

发布日期:2000-04-25

Synthesis, crystal structure, transesterifications of the complex of β- butoxycarbonylethyltin trichlorides with schiff base ligands

Li Zhongfang;Wang Suwen;Tan Xiaoyao;Fu Fangxin;Pan Huade

NE Normal Univ, Dept Chem.Changchun(130024)

Published:2000-04-25

Abstract

Title complex n-BuO2CCH2CH2SnCl2SnCl3. (2 -HOC6H4CH=NC6H4OMe-4') was synthesized and characterized by elemental analysis, UV - Vis, IR, ^1H NMR. The crystal structure was determined by the X - ray diffraction analysis. The crystal belong to monoclinic system, system, space group P2 1/c with a =1.4661(3), b =).9307(2), c =1.7888(4)nm, β=94. 04(3)°; Z=4. The complex exists as a discrete molecule, and the in atom attains a distorted octahedral geometry vis the coordination of intramolecular carbonyl oxygen and [henolic oxygen of the Schiff base. The coordination number of tin atom is 6. The transesterification ot title complex with ROH was studied and 8 new complexes RO2CCH2CH2SnCl3. (2-HOC6H4CH = NC6H4OM2 -4') (R=Me, Et, Pr, i - Bu, n - Am, i-Am, Cl - C2H4, (CH3CH2)2CHCH2 -) were obtained. The possibel mechanism is suggested

Key words: TIN COMPLEX, SCHIFF BASE, TRANSESTERIFICATION, CRYSTAL STRUCTURE

CLC Number:

O611.662

Cite this article

Li Zhongfang;Wang Suwen;Tan Xiaoyao;Fu Fangxin;Pan Huade. Synthesis, crystal structure, transesterifications of the complex of β- butoxycarbonylethyltin trichlorides with schiff base ligands[J]. Chin. J. Org. Chem., 2000, 20(2): 206-212.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Qifan Wang, Yuanquan Zhang, Li Xing, Yuanxiang Zhou, Chenyu Gong, Bangcan He, Nian Zhang, Yongjun Wu, Wei Xue. Design, Synthesis and Biological Activity of Myricetin Derivatives Containing 1,2,4-Triazolo[3,4-b]-1,3,4-thiadiazole [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1525-1536.
[2]	Jing Wang, Linlin Wu, Qian Wang. Synthesis and Characterization of New Indeno[1,2-b]fluorene-6,12-dione Derivatives [J]. Chinese Journal of Organic Chemistry, 2023, 43(1): 223-228.
[3]	Chensheng Yu, Han Wang, Lijing Min, Liang Han, Jianjun Shi, Xinghai Liu. Synthesis, Cyrstal Structure and Fungicidal Activity of New Triazole Compounds Containing Trifluoromethylphenyl Moiety [J]. Chinese Journal of Organic Chemistry, 2021, 41(11): 4498-4503.
[4]	He Mei, He Chaofan, Liu Ling, Ye Jiao, Hu Aixi, Chen Yun, Xu Lujie, Liu Ailin. Synthesis, Crystal Structure and Neuraminidase Inhibitory Activity of 1,2,4-Triazole-3-sulfide Derivatives [J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2402-2410.
[5]	Wang Jing, Jin Zhaohui, Ma Rong, Hao Yinjian, Wang Yijun, Li Ningbo, Xu Xinhua. Efficient Synthesis of 1,4-Dihydropyridines and Polyhydroquinolines Catalyzed by Novel Schiff Base Zirconium Lewis Acid [J]. Chinese Journal of Organic Chemistry, 2020, 40(4): 969-977.
[6]	Zhang Chenglu, Wang Huayu, Yu Xiangkun, Yang Jingyi, Li Chuanyin, Gong Rongqin, Song Fulu, Sun Yuedong. Synthesis of Amide Thioether Bridged 1,3-Selenazole and 1,2,4-Triazole Derivatives and Their Inhibitory Activity against Cell Division Cycle Phosphatase B (Cdc25B) [J]. Chinese Journal of Organic Chemistry, 2020, 40(2): 432-439.
[7]	Wu Shaojie, Lu Yiming, Lei Zhuonan, Jiang Yan, Zhang Wenhui, Qi Le, Ma Haixia, Ren Yinghui. Synthesis, Biological Activity and Molecular Docking of 4-Amino-5-substituted-1,2,4-triazole-3-thione Schiff Base [J]. Chin. J. Org. Chem., 2019, 39(7): 1939-1944.
[8]	Jia Huijie, Han Limin, Zhu Ning, Gao Yuanyuan, Wang Yaqi, Suo Quanling. A Study on Recognition Property of Acetylferrocenyl Benzothiazole to Al³⁺, Cr³⁺ and Fe³⁺ [J]. Chin. J. Org. Chem., 2019, 39(6): 1753-1760.
[9]	Ma Hongpeng, Bai Chaolumen, Bao Yongsheng. Nano-Gold Catalyzed Transesterification of (Hetero) aryl Esters with Alkyl Halides via C-O Activation [J]. Chin. J. Org. Chem., 2019, 39(3): 734-746.
[10]	Zhao Bangtun, Fu Huimin, Chen Xiaoji, Zhu Weimin. A New Method for Synthesizing Tetrathiafulvalene Vinylogues [J]. Chin. J. Org. Chem., 2018, 38(8): 2116-2121.
[11]	Hao Yunpeng, Xie Zhengfeng, Bao Wanrui, Wang Xin, Shi Wei. Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide [J]. Chin. J. Org. Chem., 2018, 38(8): 2109-2115.
[12]	Zhang Youming, Han Bingbing, Lin Qi, Mao Pengpeng, Chen Jinfa, Yao Hong, Wei Taibao. Synthesis and Fe³⁺ Sensing Properties of the Chemosensor Based on Functionalized Naphthalimide Schiff Base Derivative [J]. Chin. J. Org. Chem., 2018, 38(7): 1800-1805.
[13]	Shi Juan, Zhang Zunting. Synthesis and Fluorescent Property of Benzo [c]coumarin Carboxylic Derivatives [J]. Chin. J. Org. Chem., 2018, 38(6): 1462-1468.
[14]	Zhang Weijie, Xu Li, Song Jinsheng, Ma Zhiying, Wang Hua. Synthesis of Saddle-Shaped Cyclooctatetrathiophene-Triazine Derivatives and Their Aggregation Induced Emissions (AIE) Properties [J]. Chin. J. Org. Chem., 2018, 38(5): 1119-1125.
[15]	Ding Haixin, Li Chuang, Dong Xiangyou, Cao Banpen, Zhang Ning, Hong Sanguo, Xiao Qiang. First Total Synthesis of Marine Natural Nucleoside Kipukasin D [J]. Chin. J. Org. Chem., 2018, 38(12): 3351-3355.

β- 丁氧酯基三氯化锡与席夫碱配合物的合成、结构与酯交换反应

Synthesis, crystal structure, transesterifications of the complex of β- butoxycarbonylethyltin trichlorides with schiff base ligands

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments