Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide

doi:10.6023/cjoc201804034

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (8): 2109-2115.DOI: 10.6023/cjoc201804034 Previous Articles Next Articles

Special Issue: 荧光探针-生物传感合辑；有机超分子化学合辑

Articles

一种新型比色荧光增强型CN^-探针的合成与性能研究

郝云鹏^a, 解正峰^a,b, 包万睿^b, 王馨^b, 石伟^a

a 西南石油大学化学化工学院成都 610500;
b 新疆大学化学化工学院乌鲁木齐 830046

收稿日期:2018-04-17 修回日期:2018-05-15 发布日期:2018-05-24
通讯作者: 解正峰, 石伟 E-mail:xiezhf@swpu.edu.cn;shiwei80@swpu.edu.cn
基金资助:
国家自然科学基金（Nos.21262034，21364013）、西南石油大学精细化学品青年科技创新团队（No.2017CXTD05）资助项目.

Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide

Hao Yunpeng^a, Xie Zhengfeng^a,b, Bao Wanrui^b, Wang Xin^b, Shi Wei^a

a College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500;
b College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046

Received:2018-04-17 Revised:2018-05-15 Published:2018-05-24
Contact: 10.6023/cjoc201804034 E-mail:xiezhf@swpu.edu.cn;shiwei80@swpu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21262034, 21364013), and the Youth Science and Technology Innovation Team of Southwest Petroleum University (No. 2017CXTD05).

1. Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide.PDF(825KB)

Abstract

A novel fluorescent "turn-on" probe 7-(dibutylamino)-2'-((2-hydroxybenzylidene)amino)-3-methyl-1-phenyl-1H-spiro[chromeno[2,3-c]pyrazole-4,1'-isoindolin]-3'-one (SCPz-S) with Schiff base structure was designed and synthesized, and characterized by ¹H NMR, ¹³C NMR and high resolution mass spectrometry (HRMS). The UV-Vis and fluorescence spectra were used to investigate the ions recognition capability of probe SCPz-S. It was excavated that the probe SCPz-S has a dual colorimetric and fluorescence response to CN^- in THF/H₂O (V:V=1930:50, 5 mmol/L Tris-HCl, pH=7.4). After adding CN^-, the system of probe SCPz-S will change from colorless to yellow, and fluorescence enhance 1060-fold at 575 nm. The sensor SCPz-S also has good anti-interference ability and a wide pH range from 3 to 12 applicable. Its LOD for CN^- is 1.121×10^-8 mol/L, and the recognition mechanism has been investigated.

Key words: spiro[chromene[2,3-c]pyrazole-4,1'-isoindoline], fluorescence, colorimetric, CN^-, Schiff base, deprotonation

Cite this article

Hao Yunpeng, Xie Zhengfeng, Bao Wanrui, Wang Xin, Shi Wei. Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide[J]. Chin. J. Org. Chem., 2018, 38(8): 2109-2115.

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一种新型比色荧光增强型CN^-探针的合成与性能研究

Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide

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一种新型比色荧光增强型CN-探针的合成与性能研究

Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide

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Abstract

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一种新型比色荧光增强型CN^-探针的合成与性能研究