Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (3): 367-371. Previous Articles     Next Articles

从N-Fmoc-L-α-氨基酸合成同系物N-Fmoc-L-β-氨基酸(II)^#

洪镛裕;廖本仁;刘波;熊飞   

  1. 华东师范大学化学系.上海(200062)
  • 发布日期:2000-06-25

Synthesis of N-Fmoc-L-α-homoamino acid from N-Fmoc-L-β -amino acid (II)

Hong Yongyu;Liao Benren;Liu Bo;Xiong Fei   

  1. E China Normal Univ, Dept Chem.Shanghai(200062)
  • Published:2000-06-25

N-Fmoc-L-β-homoglutamine and N-Fmoc-L-β-homoasparagine have been prepared by arndt-eistert synthesis from commercially available N- Fmoc-L-α-glutamine and N^α -Fmoc-N^γ-trityl-L-asparagine. By- products produced in the arrangement were discussed.

Key words: AMINO ACID, ASPARAGINE, REARRANGEMENT REACTION, DIAZOKETONE, GLUTAMINE

CLC Number: