The synthesis of asymmetrically 3, 3-disubstituted  methyl oxetanes

Abstract

With 2, 2-bis(bromomethyl)propane-1, 3-diol as a starting material, six oxetane derivatives, 3-bromomethyl-3-hydroxymethyloxetane(2), 3- ethyloxymethyl-3-hydroxymethyl oxetane(3), 3-azidomethyl-3- hydroxymethyloxetane(4), 3-azidomethyl-3-nitratomethyl oxetane(5), 3- bromomethyl-3-nitratomethyloxetane(6) and 3-ethloxymethyl-3- nitratomethyl oxetane(7) were successfully prepared. Their structures were determined with FTIR ^1H NMR, MS and elemental analysis.

Key words: ASYMMETRY UNIT, OXETANE P, AZIDE, SOLID PROPELLANTS, NITRATION, STRUCTURAL ANALYSIS

CLC Number:

O621

Cite this article

Lei Xiangyang;Feng Zengguo;Liu Lihua;Yang Yaming;Li Haihua. The synthesis of asymmetrically 3, 3-disubstituted methyl oxetanes[J]. Chin. J. Org. Chem., 2000, 20(3): 391-394.

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3, 3-不对称二取代甲基氧杂丁环的合成

The synthesis of asymmetrically 3, 3-disubstituted methyl oxetanes

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