Microwave-Assisted Synthesis and Fluorescence Characterization of Bis-1,2,4-triazine Derivatives

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (08): 1079-1082. Previous Articles Next Articles

Original Articles

微波辅助合成双1,2,4-三嗪化合物及其荧光特性研究

孙一峰*^,1，潘文龙²，吴仁涛¹，宋化灿²

(¹泰山学院化学系泰安 271021)
(²中山大学化学与化学工程学院广州 510275)

收稿日期:2005-08-25 修回日期:2006-02-20 发布日期:2006-07-26
通讯作者: 孙一峰

Microwave-Assisted Synthesis and Fluorescence Characterization of Bis-1,2,4-triazine Derivatives

SUN Yi-Feng*^,1,PAN Wen-Long²,WU Ren-Tao¹,SONG Hua-Can²

(¹Department of Chemistry, Taishan University, Taian 271021)
(²School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275)

Received:2005-08-25 Revised:2006-02-20 Published:2006-07-26
Contact: SUN Yi-Feng

Abstract

Five bis-1,2,4-triazine derivatives were synthesized by the reaction of benzil, dihydrazide and ammonium acetate in acetic acid under microwave irradiation with yields of 72%～85%. The structures of the title compounds were characterized by elemental analysis, IR, ¹H NMR, MS and fluorescence spectra. The effect of metal ions on fluorescence characterization of compound 3a was investigated. The microwave irradiation dramatically shortened the reaction times, affording the desired products in high yields. The selective interaction between metal ions (Cu^2＋, Ni^2＋) and 3a led to obvious fluorescence quenching.

Key words: fluorescence characterization, fluorescence quenching, microwave-assisted synthesis, ion recognition, 1,2,4-triazine

Cite this article

SUN Yi-Feng*^,1,PAN Wen-Long²,WU Ren-Tao,SONG Hua-Can². Microwave-Assisted Synthesis and Fluorescence Characterization of Bis-1,2,4-triazine Derivatives[J]. Chin. J. Org. Chem., 2006, 26(08): 1079-1082.

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微波辅助合成双1,2,4-三嗪化合物及其荧光特性研究

Microwave-Assisted Synthesis and Fluorescence Characterization of Bis-1,2,4-triazine Derivatives

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