Synthesis and Herbicidal Activity of Ethoxyethyl 2-Cyano-3- (substituted)pyridinemethylamino-3-(substituted)acrylates

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (9): 1232-1238. Previous Articles Next Articles

Original Articles

2-氰基-3-取代吡啶甲胺基-3-取代丙烯酸乙氧乙酯的合成和除草活性研究

刘玉秀，李姮，赵奇奇，汪清民*，黄润秋

(南开大学元素有机化学研究所元素有机化学国家重点实验室天津 300071)

收稿日期:2005-08-05 修回日期:1900-01-01 发布日期:2006-09-11
通讯作者: 汪清民

Synthesis and Herbicidal Activity of Ethoxyethyl 2-Cyano-3- (substituted)pyridinemethylamino-3-(substituted)acrylates

LIU Yu-Xiu,LI Heng,ZHAO Qi-Qi,WANG Qing-Min*,HUANG Run-Qiu

(State Key Laboratory of Elemento-organic Chemistry, Institute of Elemento-organic Chemis-try,
Nankai University, Tianjin 300071)

Received:2005-08-05 Revised:1900-01-01 Published:2006-09-11
Contact: WANG Qing-Min

Abstract

A series of 2-cyano-3-(substituted)pyridinemethylaminoacrylates were synthesized as herbicidal inhibitors of photosystem II (PSII) electron transport and their herbicidal activities were evaluated. Some of them exhibited excellent herbicidal activities, especially (Z)-ethoxyethyl 2-cyano-3-isopropyl-3-(2- alkoxypyridin-3-yl)methaneaminoacrylate. These results indicated that a suitable substituent at the 2-position of pyridine ring and a well-fit group at the 3-position of acrylate were both essential for high her-bicidal activity.

Key words: photosystem II (PSII), pyridine ring, electron transport inhibitor, herbicidal activity, cyanoacrylate

Cite this article

LIU Yu-Xiu,LI Heng,ZHAO Qi-Qi,WANG Qing-Min*,HUANG Run-Qiu. Synthesis and Herbicidal Activity of Ethoxyethyl 2-Cyano-3- (substituted)pyridinemethylamino-3-(substituted)acrylates[J]. Chin. J. Org. Chem., 2006, 26(9): 1232-1238.

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2-氰基-3-取代吡啶甲胺基-3-取代丙烯酸乙氧乙酯的合成和除草活性研究

Synthesis and Herbicidal Activity of Ethoxyethyl 2-Cyano-3- (substituted)pyridinemethylamino-3-(substituted)acrylates

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