Study on Synthesis of Tertiary Arylamines of 1,4-Bianilinophenylene and 4,4'-Bianilinobiphenyl and Their Light Emitting Property

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (9): 1239-1242. Previous Articles Next Articles

Original Articles

苯二胺和联苯二胺类叔芳胺的合成及发光性能的研究

余明新*^,a,b，温伟江^a，郑建鸿^b

(^a浙江大学化学系杭州 310027)
(^b台湾清华大学化学系新竹 30043)

收稿日期:2005-09-27 修回日期:1900-01-01 发布日期:2006-09-11
通讯作者: 余明新

Study on Synthesis of Tertiary Arylamines of 1,4-Bianilinophenylene and 4,4'-Bianilinobiphenyl and Their Light Emitting Property

YU Ming-Xin*^,a,b,WEN Wei-Jiang^a,CHENG Chien-Hong^b

(^aDepartment of Chemistry, Zhejiang University, Hangzhou 310027)
(^bDepartment of Chemistry, Tsinghua University, Hsinchu 30043)

Received:2005-09-27 Revised:1900-01-01 Published:2006-09-11
Contact: YU Ming-Xin

Abstract

1,4-Bianilinophenylene and 4,4'-bianilinobiphenyl reacted with aryl bromide with the catalysis of Pd(OAc)₂/P(t-Bu)₃ at 120 ℃ in o-xylene to afford the organic light emitting diode (OLED) material of tertiary arylamine of reactant diamine. Melting points of the products are above 300 ℃, and their structures were characterized by ¹H NMR, ¹³C NMR, ¹³C (DEPT), HRMS methods. Light emitting properties were exam-ined by UV-Vis, photoluminescence and DSC spectra.

Key words: 1,4-bianilinophenylene, light emitting property, 4,4'-bianilinobiphenyl, tertiary arylamine, palladium catalyst

Cite this article

YU Ming-Xin*^,a,b,WEN Wei-Jiang^a,CHENG Chien-Hong^b. Study on Synthesis of Tertiary Arylamines of 1,4-Bianilinophenylene and 4,4'-Bianilinobiphenyl and Their Light Emitting Property[J]. Chin. J. Org. Chem., 2006, 26(9): 1239-1242.

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苯二胺和联苯二胺类叔芳胺的合成及发光性能的研究

Study on Synthesis of Tertiary Arylamines of 1,4-Bianilinophenylene and 4,4'-Bianilinobiphenyl and Their Light Emitting Property

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