Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (05): 674-677. Previous Articles     Next Articles

Reports

基于联吡啶的π-共轭有机电致发光分子的合成和光学性质研究

夏艳,周子彦,孟凡坤,吴学*   

  1. (延边大学长白山生物功能因子省部共建教育部重点实验室 延吉133002)
  • 收稿日期:2006-01-26 修回日期:2006-09-13 发布日期:2007-05-10
  • 通讯作者: 吴学

π-Conjugated Organic Electroluminescent Molecules Based on Bipyridyl: Synthesis and Optical Properties

XIA Yan, ZHOU Zi-Yan, MENG Fan-Kun, WU Xue*   

  1. (Key Laboratory of Organism Functional Factors of the Changbai Mountain, Ministry of Education,
    Yanbian University, Yanji 133002)
  • Received:2006-01-26 Revised:2006-09-13 Published:2007-05-10
  • Contact: WU Xue

A series of novel π-conjugated molecules based on bipyridyl were synthesized by Wittig-Horner reaction. Their structures were characterized by 1H NMR, 13C NMR, IR, MS spectra and elemental analysis. All the compounds synthesized exhibit remarkable thermal stability as determined by thermal gravimetric analysis (TGA). The photoluminescence (PL) emission maximum peaks of materials prepared are in the range of 439~441 nm corresponding to blue light re-gion.

Key words: bipyridyl, blue light, thermal gravimetric unalysis, thermal stability, Wittig-Horner reaction