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Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (03): 535-537. Previous Articles     Next Articles

Reports

单体卟啉和二聚体卟啉的合成及其三阶光学非线性的研究

郑文琦a,c，单凝a，裴松皓b，彭慰先b，王杏乔*,a   

  1. (a吉林大学化学学院 长春 130021)
    (b吉林大学物理学院 长春 130021)
    (c吉林建筑工程学院基础科学部 长春 130021)
  • 收稿日期:2007-03-17 修回日期:2007-08-07 发布日期:2008-03-18
  • 通讯作者: 王杏乔

Synthesis of Porphyrin Monomers and Porphyrin Dimers andStudy on Their Third-Order Optical Nonlinearities

ZHENG Wen-Qia,c,SHAN Ninga,PEI Song-Haob,PENG Wei-Xianb
WANG Xing-Qiao*,a   

  1. (a College of Chemistry, Jilin University, Changchun 130021)
    (b College of Physics, Jilin University, Changchun 130021)
    (c Basic Science Department, Jilin Architectural and Civil Engineering Institute, Changchun 130021)
  • Received:2007-03-17 Revised:2007-08-07 Published:2008-03-18
  • Contact: WANG Xing-Qiao*

Several porphyrin monomers and porphyrin dimers were synthesized and their third-order optical nonlinearities were determined. Different peripheries of the porphyrin macrocycle and bridging groups had influence on third-order optical nonlinearities. Experimental results confirmed that the nonlinearities polarization rates increased along with the enhancement of electron density of porphyrin macrocycle.

Key words: porphyrin dimer, third-order optical nonlinearity, porphyrin monomer