Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (04): 732-735. Previous Articles     Next Articles

Reports

苯乙烯相连的卟啉-三芳胺共轭体的合成及表征

薛金强,冯亚青*,汪磊,吴玲卉   

  1. (天津大学化工学院 天津 300072)
  • 收稿日期:2007-06-11 修回日期:2007-09-25 发布日期:2008-04-17
  • 通讯作者: 冯亚青

Synthesis and Characterization of Conjugates ofPorphy-rin-triarylamine Linked by Styrene

XUE Jin-Qiang,FENG Ya-Qing*,WANG Lei,WU Ling-Hui   

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072)
  • Received:2007-06-11 Revised:2007-09-25 Published:2008-04-17
  • Contact: FENG Ya-Qing

The compounds 4-[4-(N,N-diphenylamino)styryl]benzaldehyde, 4-[4-(N,N-di-p-tolylamino)- styryl]benzaldehyde and 4-[4-(N,N-di-4-methoxyphenylamino)styryl]benzaldehyde were obtained by a Wit-tig-Horner reaction of 4-diarylaminobenzaldehyde with diethyl 4-(diethoxymethyl)benzylphosphonate, then a series of new porphyrin-triarylamine conjugates linked by styrene bridges were synthesized by refluxing compounds 4 and pyrrole in propionic acid and characterized by 1H NMR, 13C NMR, MS and UV-vis techniques.

Key words: triarylamine, porphyrin, conjugate, styrene, Wittig-Horner reaction