Preparation and Crystal Structure of 9,9-Dimethyl-2-(4-methoxy- phenyl)-4-phenyl-9H-pyrido[1,2-a]indolium Perchlorate underMicrowave Radiation

Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (2): 353-355. Previous Articles Next Articles

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9,9-二甲基-2-(4-甲氧基苯基)-4-苯基-9H-吡啶并[1,2-a]吲哚高氯酸盐的微波合成及晶体结构

陈栓虎*，胥学旺，王娜妮

(西北大学化学系西安 710069)

收稿日期:2007-05-14 修回日期:2007-08-24 发布日期:2008-02-01
通讯作者: 陈栓虎

Preparation and Crystal Structure of 9,9-Dimethyl-2-(4-methoxy- phenyl)-4-phenyl-9H-pyrido[1,2-a]indolium Perchlorate underMicrowave Radiation

CHEN Shuan-Hu*,XU Xue-Wang,WANG Na-Ni

(Department of Chemistry, Northwest University, Xi'an 710069)

Received:2007-05-14 Revised:2007-08-24 Published:2008-02-01
Contact: CHEN Shuan-Hu

Abstract

9,9-Dimethyl-2-(4-methoxyphenyl)-4-phenyl-9H-pyrido[1,2-a]indolium perchlorate was synthesized by mixing 2,3,3-trimethyl-3H-indolium perchlorate and 1-phenyl-3-(4-methoxyphenyl)-2-propen-1- one under microwave radiation. The structure was characterized by elemental analysis and IR, which single structure was determined by X-ray diffraction analysis. It belongs to orthorhombic system with space group Pca2₁ and cell parameters: a＝2.7923(6) nm, b＝0.92126(17) nm, c＝1.8345(4) nm, V＝4.7190(16) nm³, D_c＝1.345 g/cm³, μ＝0.201 mm^－1, F(000)＝2000, Z＝8, R₁＝0.0566 and wR₂＝0.1320.

Key words: crystal structure, 9,9-dimethyl-2-(4-methoxyphenyl)-4-phenyl-9H-pyrido[1,2-a]indolium perchlorate, microwave radiation method

Cite this article

CHEN Shuan-Hu*,XU Xue-Wang,WANG Na-Ni. Preparation and Crystal Structure of 9,9-Dimethyl-2-(4-methoxy- phenyl)-4-phenyl-9H-pyrido[1,2-a]indolium Perchlorate underMicrowave Radiation[J]. Chin. J. Org. Chem., 2008, 28(2): 353-355.

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9,9-二甲基-2-(4-甲氧基苯基)-4-苯基-9H-吡啶并[1,2-a]吲哚高氯酸盐的微波合成及晶体结构

Preparation and Crystal Structure of 9,9-Dimethyl-2-(4-methoxy- phenyl)-4-phenyl-9H-pyrido[1,2-a]indolium Perchlorate underMicrowave Radiation

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