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Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (06): 865-870. Previous Articles     Next Articles

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9-[(4,5-二硫十六烷基)-1,3-二硫环戊烯-2-亚基]-10(9H)-蒽酮的合成及光电性质研究

朱玉兰*,1,2，尹起范1，马奎蓉1，曹丽1,2，荆晓1,2，仲慧1   

  1. 1淮阴师范学院化学化工学院 江苏省低维材料化学重点建设实验室 淮安 223300)
    (2东北师范大学化学学院 长春 130024
  • 收稿日期:2009-08-24 修回日期:2009-11-10 发布日期:2010-01-20
  • 通讯作者: 朱玉兰 E-mail:ylzhu1998@126.com
  • 基金资助:

    国家级.国家自然科学基金

Synthesis and Photo-electric Properties of 9-[4,5-Bis-(hexadecylthio)-1,3-dithiol-2-ylidene]anthracen-10(9H)-one

Zhu Yulan*,1,2 Yin Qifan1 Ma Kuirong1 Cao Li1,2 Jing Xiao1,2 Zhong Hui1   

  1. 1 Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian 223300)
    (2 School of Chemistry, Northeast Normal University, Changchun 130024)
  • Received:2009-08-24 Revised:2009-11-10 Published:2010-01-20

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A new 9-[4,5-bis-(hexadecylthio)-1,3-dithiol-2-ylidene]anthracen-10(9H)-one (d) has been synthesized. The molecular structure was characterized by 1H NMR, 13C NMR, TOFMS and IR spectra. The photocurrent response experiment was performed with the electrochemical workstation. The photocurrent is relatively stable and reversible, which means that this system has an obvious property of photo-electric transfer. The geometry structure of the product was optimized using Gaussian 03 quantum chemical program package, and the method of density functional theory (DFT) at the level of 6-31G(d). The calculated results are in agreement with the experimental values. The research shows that this compound displays an intramolecular charge-transfer property.

Key words: anthraquinone derivative, charge transfer, photo-electric property, DFT