Selective Oxidation of Benzyl Alcohols Using RuCl3•3H2O/DCHA in Air

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (04): 516-520. Previous Articles Next Articles

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RuCl₃•3H₂O/DCHA体系在空气中对苄醇的选择性氧化

范卫永，叶东鼐，张世勇，舒磊，刘良先*

(赣南师范学院化学与生命科学学院赣州 341000)

收稿日期:2010-06-15 修回日期:2010-09-23 发布日期:2010-11-26
通讯作者: 刘良先 E-mail:lxliu@xmu.edu.cn

Selective Oxidation of Benzyl Alcohols Using RuCl₃•3H₂O/DCHA in Air

FAN Wei-Yong, YE Dong-Nai, ZHANG Shi-Yong, SHU Lei, LIU Liang-Xian

(Department of Chemistry and Biology, Gannan Teachers College, Ganzhou 341000)

Received:2010-06-15 Revised:2010-09-23 Published:2010-11-26

Abstract

The aerobic oxidation of benzylic alcohols to aldehydes was performed in a RuCl₃•3H₂O-dicyclohexylamine (DCHA) catalyst system under air atmosphere at room temperature. It is important that RuCl₃•3H₂O-DCHA system displays a preference for the primary versus secondary benzylalcohol in intermolecular competition experiments and a preference for the primary versus the secondary hydroxyl group of a benzylic diol in intramolecular competition experiments. The broad scope, mild reaction conditions, and experimental ease of this transformation have made it a valuable alternative to current available methods.

Key words: ruthenium trichloride, dicyclohexylamine, benzylic alcohol, aerobic oxidation

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FAN Wei-Yong, YE Dong-Nai, ZHANG Shi-Yong, SHU Lei, LIU Liang-Xian. Selective Oxidation of Benzyl Alcohols Using RuCl₃•3H₂O/DCHA in Air[J]. Chin. J. Org. Chem., 2011, 31(04): 516-520.

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RuCl₃•3H₂O/DCHA体系在空气中对苄醇的选择性氧化

Selective Oxidation of Benzyl Alcohols Using RuCl₃•3H₂O/DCHA in Air

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RuCl3•3H2O/DCHA体系在空气中对苄醇的选择性氧化