Crytal Structure of Cucurbituril Complex with Hydroxy-Bearing Dia-mine Compound and Its Interaction

Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (12): 2175-2180. Previous Articles Next Articles

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瓜环与含羟基功能基二胺包结配合物的晶体结构及相互作用的研究

肖志友 ; 张奇龙; 张云黔; 朱必学*

(贵州大学化学系贵阳 550025)

收稿日期:2008-03-01 修回日期:2008-05-09 发布日期:2008-12-28
通讯作者: 朱必学*

Crytal Structure of Cucurbituril Complex with Hydroxy-Bearing Dia-mine Compound and Its Interaction

XIAO, Zhi-You; ZHANG, Qi-; ZHANG, Yun-Qian; ZHU, Bi-Xue*

(Department of Chemistry, Guizhou University, Guiyang 550025)

Received:2008-03-01 Revised:2008-05-09 Published:2008-12-28
Contact: ZHU, Bi-Xue

Abstract

The hydroxy-bearing diamine guest, 1,3-bis(2-aminophenoxy)-2-propanol, was synthesized and characterized. The crystal structure of the inclusion complex of cucurbituril (Q[8]) with 1,3-bis(2-
aminophenoxy)-2-propanol was determined by X-ray diffraction analysis. The results showed that the Q[8] bound the guest to form an inclusion complex in a ratio of 1∶2, and intermolecular π-π interations existed between the benzene rings of the two guest molecules in the cavity of Q[8]. The interaction of the host-guest system was investigated by 1H NMR techniques and UV-Vis spectroscopy, showing a good agreement with the crystal structure of the host-guest complex.

Key words: 1,3-bis(2-aminophenoxy)-2-propanol, crystal structure, cucurbituril (Q[8])

Cite this article

XIAO, Zhi-You; ZHANG, Qi-; ZHANG, Yun-Qian; ZHU, Bi-Xue*

. Crytal Structure of Cucurbituril Complex with Hydroxy-Bearing Dia-mine Compound and Its Interaction[J]. Chin. J. Org. Chem., 2008, 28(12): 2175-2180.

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瓜环与含羟基功能基二胺包结配合物的晶体结构及相互作用的研究

Crytal Structure of Cucurbituril Complex with Hydroxy-Bearing Dia-mine Compound and Its Interaction

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