Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (2): 176-180. Previous Articles     Next Articles

Original Articles

某些N-芳基-(1'-羧甲基二茂铁基)乙酰胺的合成与表征

边占喜;范瑞兰;李逢泽   

  1. 内蒙古大学化学系.呼和浩特(010021)
  • 发布日期:1999-04-25

Synthesis and characterization of some N-aryl-(1'- carboxymethylferrocenyl)-acetamides

Bian Zhanxi;Fan Ruilan;Li Fengze   

  1. Inner Mongolia Univ, Dept Chem.Hohhot(010021)
  • Published:1999-04-25

14 N-aryl-(1'-carboxymethylferrocenyl)-acetamides have been synthesized by reaction of 1, 1'-ferrocenediacetic acid anhydride with aromatic amines. The reactivities of the aromatic amines in the reaction have been studied. And the structures of the products were characterized by elementary analysis, IR and ^1H NMR. The reaction of N-2-hydroxy (phenyl)-(1'-carboxymethylferrocenyl)-acetamide with CuCl~2.2H~2O was also tentatively studied. The composition of the corresponding cupper complex (LCuCl~2.2H~2O) was confirmed by elementary analysis.

Key words: NMR SPECTROMETRY, ACETAMIDE P, ELEMENTAL ANALYSIS, BENZAMINE P, INFRARED SPECTROPHOTOMETRY, STRUCTURE CHARACTERISTICS, FERROCENE, FERROCENE P

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