The crystal and molecular structure of the adduct of bis(O,O-dibutyldithiophosphato)nickel (II) with pyridine

Chin. J. Org. Chem. ›› 1987, Vol. 7 ›› Issue (5): 369-373. Previous Articles Next Articles

双-(O,O'-二正丁基二硫代磷酸酯)合镍-二吡啶加合物的晶体结构和分子结构

刘世雄;林墀昌;徐正;俞运鹏;游效曾

福州大学结构化学研究实验室;南京大学配位化学研究所

发布日期:1987-10-25

The crystal and molecular structure of the adduct of bis(O,O-dibutyldithiophosphato)nickel (II) with pyridine

LIU SHIXIONG;LIN CHICHANG;XU ZHENG;YU YUNPENG;YOU XIAOZENG

Published:1987-10-25

Abstract

The title (1:2) adduct is monoclinic, space group P21/c, with a 13.753(3), b 9.256(2), c 15.306(3) ? and b 113.80(1)? d. (calcd.) = 1.300 for Z = 2. Final R = 0.062. Atomic coordinates are given. Ni is coordinated by 4 S atoms in the plane and 2 pyridine mols in trans positions. The significant variations in the Ni-S bond lengths and angles in the chelate ring can be explained using a simple electrostatic model.

Key words: CRYSTAL STRUCTURE DETERMINATION, PYRIDINE P, MOLECULAR STRUCTURE, PHOSPHORIC ACID ESTER, NICKEL COMPLEX, PHOSPHORODITHIOIC ACID P

CLC Number:

O74
O611.662

Cite this article

LIU SHIXIONG;LIN CHICHANG;XU ZHENG;YU YUNPENG;YOU XIAOZENG. The crystal and molecular structure of the adduct of bis(O,O-dibutyldithiophosphato)nickel (II) with pyridine[J]. Chin. J. Org. Chem., 1987, 7(5): 369-373.

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双-(O,O'-二正丁基二硫代磷酸酯)合镍-二吡啶加合物的晶体结构和分子结构

The crystal and molecular structure of the adduct of bis(O,O-dibutyldithiophosphato)nickel (II) with pyridine

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