Inclusion Compound of β-Cyclodextrin with p-Azidobenzoic Acid

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (11): 1303-1305. Previous Articles Next Articles

对叠氮苯甲酸与β-环糊精的包合作用

朱晋熠;刘玲;芦昌盛;孟庆金

南京大学配位化学研究所;云南师范大学化学化工学院

发布日期:2003-11-25

Inclusion Compound of β-Cyclodextrin with p-Azidobenzoic Acid

Zhu Jinyi;Liu Ling;Lu Changsheng;Meng Qingjin

Institute of Coordination Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University;College of Chemistry and Chemical Engineering, Yunnan Normal University

Published:2003-11-25

Abstract

An inclusion compound of p -azidobenzoic acid with β-cyclodextrin (β-CD) was prepared and characterized by thermogravimetry, IR, ~1H NMR and UV spectroscopies. The thermal stability of p-azidobenzoic acid was significantly improved after inclusion, and the decomposition temperature difference between the pure p-azidobenzuic acid and that in conclusion compound was +115 ℃. By using data of UV spectroscopy, the binding constant of the inclusion compound was estimated to be (7933 ± 192) L·mol~(-1).

Key words: AZODES;BENZENECARBOXYLIC ACID P;CYCLODEXTRIN;CLATHRATES;IR;TG, NMR

CLC Number:

O621

Cite this article

Zhu Jinyi;Liu Ling;Lu Changsheng;Meng Qingjin. Inclusion Compound of β-Cyclodextrin with p-Azidobenzoic Acid[J]. Chin. J. Org. Chem., 2003, 23(11): 1303-1305.

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对叠氮苯甲酸与β-环糊精的包合作用

Inclusion Compound of β-Cyclodextrin with p-Azidobenzoic Acid

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