Nucleophilic Organocatalysis through Umpolung

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Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (05): 545-564. Next Articles

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经过极性反转的亲核有机催化

于海珠，傅尧，刘磊，郭庆祥*

(中国科学技术大学化学系合肥 230026)

收稿日期:2006-03-06 修回日期:1900-01-01 发布日期:2007-05-10
通讯作者: 郭庆祥

Nucleophilic Organocatalysis through Umpolung

YU Hai-Zhu, FU Yao, LIU Lei, GUO Qing-Xiang*

(Department of Chemistry, University of Science and Technology of China, Hefei 230026)

Received:2006-03-06 Revised:1900-01-01 Published:2007-05-10

Contact: GUO Qing-Xiang

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Abstract

In this review the recent advances in this field are summarized and the catalysts using C, N, P and S as the nucleophilic center were surveyed. The performances of different catalysts in a variety of reactions are analyzed. The possible umpolung mechanisms of these catalysts are discussed.

Key words: umpolung, heterocyclic carbene, nucleophilic organocatalysis

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YU Hai-Zhu, FU Yao, LIU Lei, GUO Qing-Xiang*. Nucleophilic Organocatalysis through Umpolung[J]. Chin. J. Org. Chem., 2007, 27(05): 545-564.

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[1]	Dengpeng Xia, Jinyun Luo, Lin He, Zhihua Cai, Guangfen Du. N-Heterocyclic Carbene-Catalyzed Synthesis of Pentafluorophenyl Sulfides [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 622-630.
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[5]	Xinyu Zhang, Huihui Geng, Shilei Zhang, Wei Wang, Xiaobei Chen. A Method for the Synthesis of Deuterated Benzoins Catalyzed by N-Heterocyclic Carbene [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1510-1516.
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[7]	Tingting Liu, Yucai Hu, An Shen. Mechanism of Carbon-Carbon Coupling Reactions Catalyzed by Imine-Ligand-Assisted N-Heterocyclic Carbene Palladium Complexes [J]. Chinese Journal of Organic Chemistry, 2023, 43(2): 622-628.
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[10]	Ting Yao, Jiayan Li, Jiaming Wang, Changgui Zhao. Recent Advances for the Construction of Seven-Membered Ring Catalyzed by N-Heterocyclic Carbenes [J]. Chinese Journal of Organic Chemistry, 2022, 42(4): 925-944.
[11]	Zhupeng Gao, Kai Xiang, Xuetao Xu, Yating Zhang, Daoyong Zhu. α-Benzoyloxylation of β-Dicarbonyl Compounds Involving Cyclic Trivalent Iodine Reagents [J]. Chinese Journal of Organic Chemistry, 2022, 42(11): 3766-3775.
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