Synthesis of 1-methyl-2-phenyl-3-aryl imidazolidinium iodide and phenyl-substituted one carbon unit transfer reactions

Chin. J. Org. Chem. ›› 1991, Vol. 11 ›› Issue (2): 154-159. Previous Articles Next Articles

Original Articles

碘化1-甲基-2,3-二芳基咪唑啉的合成及苯基取代的一碳单元转移反应

夏炽中;周培文;丁景范;姚子荣;赵敏灵

山西大学分子科学研究所

发布日期:1991-04-25

Synthesis of 1-methyl-2-phenyl-3-aryl imidazolidinium iodide and phenyl-substituted one carbon unit transfer reactions

XIA CHIZHONG;ZHOU PEIWEN;DING JINGFAN;YAO ZIRONG;ZHAO MINLING

Published:1991-04-25

Abstract

Four 1,2,3-trisubstituted imidazolidinium iodides I (R = H, Me, Cl, NO2) were synthesized. The electronic effects of the substituent aryl groups at N(3) on the electrophilic activity of the transferable carbon was investigated by means of 13C NMR, and the difference of 1-methyl-2-phenyl-3-(p-nitrophenyl)imidazolidinium iodide with the others was also discussed. Reaction of I with R1MgX (R1 = alkyl, cyclohexyl, Ph; X = halo) gave RCOR1.

Key words: IODINE COMPOUNDS, IMIDAZOLE P, NMR SPECTROMETRY, TRANSFER REACTIONS, C1 COMPOUNDS, BENZENE P, COENZYME

CLC Number:

O621

Cite this article

XIA CHIZHONG;ZHOU PEIWEN;DING JINGFAN;YAO ZIRONG;ZHAO MINLING. Synthesis of 1-methyl-2-phenyl-3-aryl imidazolidinium iodide and phenyl-substituted one carbon unit transfer reactions[J]. Chin. J. Org. Chem., 1991, 11(2): 154-159.

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碘化1-甲基-2,3-二芳基咪唑啉的合成及苯基取代的一碳单元转移反应

Synthesis of 1-methyl-2-phenyl-3-aryl imidazolidinium iodide and phenyl-substituted one carbon unit transfer reactions

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