Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (4): 415-418. Previous Articles     Next Articles

Original Articles

烯丙基二异雪松基硼烷的制备及其与羰基化合物的不对称反应

徐伟;丁宗彪;黄阅;陶凤岗   

  1. 复旦大学化学系
  • 发布日期:1995-08-25

The preparation of allyldiisocedrylborane and its asymmetric reactions with carbonyl compounds

XU WEI;DING ZONGBIAO;HUANG YUE;TAO FENGGANG   

  • Published:1995-08-25

The allyldiisocedrylborane (Icd~2B-CH~2CH=CH~2) , prepared from (-)-α-cedrene, undergoes asymmetric allylboration with aldehydes to from homoallylic alcohlos in about 60% e.e. while with ketiones only to give the corresponding alcohols in lower than 30% e.e..

Key words: CARBONYL COMPOUNDS, BORANES, ASYMMETRY, CEDRENE

CLC Number: