Chin. J. Org. Chem. ›› 2002, Vol. 22 ›› Issue (1): 42-45. Previous Articles     Next Articles

CBS法合成光学活性二茂铁基醇

陈维一;陆军;张雅文;沈宗旋   

  1. 苏州大学化学化工系.215006
  • 发布日期:2002-01-25

Enantioselective syntheiss of chiral 1-ferrocenyl alcohol via CBS- reduction

Chen Weiyi;Lu Jun;Zhang Yawen;Shen Zongxuan   

  1. Suzhou UnivSuzhou, Dept of chem and chem ind.苏州
  • Published:2002-01-25

Reduction of prochiral ferrocenyl ketones (2a~2e) in the presence of 10 mol% of chiral β-amino alcohols(4a~4c) provides 1-ferrocenyl alcohols(1a~1e) in high yields(>85%) with high optically purity(ee up to 96%).

Key words: BORANES, ENANTIOMORPH, REDUCTION REACTION, FERROCENE P, AMINO ALCOHOL P

CLC Number: