Reaction with isocyanate

Abstract

We have studied the electroorganic reaction of aryl and alkyl isocyanate in the system of using sacrificial magnesium anode. Aryl isocyanate yielded N, N'-disubstituted urea and alkyl isocyanate yielded N, N'-disubstituted oximide. This is because of the coupling reaction between two alkyl compounds occurred by gaining electron from cathode, and aryl isocyanate reacted with high dispersed active magnesium on the cathode.

Key words: ELECTROLYSIS, UREA, ISOCYANIC ESTERS, ANODES, ELECTRODE REACTION, MAGNESIUM

CLC Number:

O621

Cite this article

XIAO YAPING;ZHOU YIMING;BAO JIANCHUN;BEI MEIZHI;ZHOU ZHIHUA. Reaction with isocyanate[J]. Chin. J. Org. Chem., 1997, 17(2): 180-182.

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