Oxidative cleavage of 2,4-dinitrophenylhydrozones by tetrabutylammonium  peroxydisulfate

Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (1): 116-121. Previous Articles Next Articles

四正丁基过硫酸铵氧化裂解2，4-二硝基苯腙衍生物的反应研究

陈芬儿;严琼娇;彭作中;张道明;傅晗;刘继东

四川大学化学系.成都(610064);复旦大学化学系.上海(200433);武汉化工学院化学系

发布日期:2000-02-25

Oxidative cleavage of 2,4-dinitrophenylhydrozones by tetrabutylammonium peroxydisulfate

Chen Fener;Yan Qiongjiao;Peng Zuozhong;Zhang Daoming;Fu Han;Liu Jidong

Sichuan Univ, Dept Chem.Chengdu(610064);Fudan Univ, Dept Chem. Shanghai(200433)

Published:2000-02-25

Abstract

2, 4- dinitrophenylhydrazone derivatives of aldehydes and ketones were converted into the corresponding carbonyl compounds in excellent yields in 1,2- dichloroethane. Other common funtioanl groups in the molecule such as olefinic double bond, cyano, ester, acetal etc were unaffacted under these reaction conditions. The possible reation mechanism and the effects of different solvent on oxidation were investigated.

Key words: AMMONIUM PERSULFATE, OXIDATION, PYROLYSIS, HYDRAZONE P, NITRO COMPOUNDS, CARBONYL COMPOUNDS, REACTION MECHANISM

CLC Number:

O621

Cite this article

Chen Fener;Yan Qiongjiao;Peng Zuozhong;Zhang Daoming;Fu Han;Liu Jidong. Oxidative cleavage of 2,4-dinitrophenylhydrozones by tetrabutylammonium peroxydisulfate[J]. Chin. J. Org. Chem., 2000, 20(1): 116-121.

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四正丁基过硫酸铵氧化裂解2，4-二硝基苯腙衍生物的反应研究

Oxidative cleavage of 2,4-dinitrophenylhydrozones by tetrabutylammonium peroxydisulfate

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