Magnetic Nanoparticle Supported Imino-pyridine Palladium Catalyzed Suzuki Reactions

doi:10.6023/cjoc201507013

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (1): 130-136.DOI: 10.6023/cjoc201507013 Previous Articles Next Articles

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磁性纳米粒子负载亚胺吡啶钯催化Suzuki反应研究

张强, 李继航, 赵鑫

苏州科技学院化学生物与材料工程学院苏州 215009

收稿日期:2015-07-16 修回日期:2015-09-22 发布日期:2015-09-30
通讯作者: 张强 E-mail:zhangqiang005@gmail.com
基金资助:
江苏省自然科学基金(No. BK20150282)和苏州科技学院科研基金(No. XKQ201417)资助项目.

Magnetic Nanoparticle Supported Imino-pyridine Palladium Catalyzed Suzuki Reactions

Zhang Qiang, Li Jihang, Zhao Xin

School of Chemistry Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009

Received:2015-07-16 Revised:2015-09-22 Published:2015-09-30
Supported by:
Project supported by the Natural Science Foundation of Jiangsu Province (No. BK20150282) and the Scientific Research Foundation of Suzhou University of Science and Technology (No. XKQ201417).

1. Magnetic Nanoparticle Supported Imino-pyridine Palladium Catalyzed Suzuki Reactions.PDF(502KB)

Abstract

A new magnetic nanoparticle supported palladium catalyst was successfully prepared by attaching palladium acetates to imino-pyridine ligand functionalized silica-coated nano-Fe₃O₄. The as-prepared catalyst was characterized by element analysis, FTIR, TEM, XPS and ICP-AES. It was found to be an efficient catalyst for Suzuki reactions in aqueous medium. And the reactions of various aryl bromides with arylboronic acids could be carried out under air and low Pd loading conditions with 83%～98% yields. Moreover, the catalyst could be easily recovered by magnetic separation and reused five times without a significant loss of catalytic activity.

Key words: magnetic nanoparticle, palladium catalyst, Suzuki reaction, Schiff base

Cite this article

Zhang Qiang, Li Jihang, Zhao Xin. Magnetic Nanoparticle Supported Imino-pyridine Palladium Catalyzed Suzuki Reactions[J]. Chin. J. Org. Chem., 2016, 36(1): 130-136.

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磁性纳米粒子负载亚胺吡啶钯催化Suzuki反应研究

Magnetic Nanoparticle Supported Imino-pyridine Palladium Catalyzed Suzuki Reactions

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