Progress in Monoprotection of Diols

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Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (03): 285-291. Previous Articles Next Articles

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二醇的单保护反应研究进展

朱磊¹,2，曹德榕*^,1

(¹中国科学院广州化学研究所纤维素化学重点实验室广州 510650)
(²中国科学院研究生院北京 100039)

收稿日期:2005-05-24 修回日期:2005-08-09 发布日期:2006-02-28
通讯作者: 曹德榕

Progress in Monoprotection of Diols

ZHU Lei¹,2,CAO De-Rong*^,1

(¹Key Laboratory of Cellulose and Lignocellulosics Chemistry, Guangzhou Institute of Chemis-try,
Chinese Academy of Sciences, Guangzhou 510650)
(²Graduate School of the Chinese Academy of Sciences, Beijing 100039)

Received:2005-05-24 Revised:2005-08-09 Published:2006-02-28

Contact: CAO De-Rong

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Abstract

The recent advances in the selective monoprotection of diols are reviwed. The monoprotection of diols could be realized by a lot of organic reactions, such as monoetherification and monoesterification of diols. The development of monoprotection of diols by the chiral reagents and bio-catalysts and the application of monoprotection of diols in the synthesis of natural products are also discussed.

Key words: diol, monoprotection, selective reaction, review

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ZHU Lei^1,2,CAO De-Rong*^,1. Progress in Monoprotection of Diols[J]. Chin. J. Org. Chem., 2006, 26(03): 285-291.

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[1]	Shouyi Cen, Zhipeng Zhang. Synthesis of Biphenanthrol-Based Confined Chiral Phosphoric Acid [J]. Chinese Journal of Organic Chemistry, 2022, 42(8): 2574-2581.
[2]	Xiaolong Fang, Bin Li, Jie Jin, Ning Duan. Homogeneous Catalytic Hydrogenation of Dimethyl Malonate into 1,3-Propanediol [J]. Chinese Journal of Organic Chemistry, 2022, 42(5): 1407-1413.
[3]	Lihua Wang, Xushun Gong, Ting Lei, Shizhi Jiang. Research Progress on Asymmetric Synthesis of Flavanones [J]. Chinese Journal of Organic Chemistry, 2022, 42(3): 758-769.
[4]	Yuxuan Zhang, Limin Xu, Yan Lu, Zhaoguo Zhang. Progress in Asymmetric Catalytic Reduction of Diketones [J]. Chinese Journal of Organic Chemistry, 2022, 42(10): 3221-3239.
[5]	Xin Li, Qiuling Song. Chiral Borane-Catalyzed Enantioselective Reactions [J]. Chinese Journal of Organic Chemistry, 2022, 42(10): 3143-3151.
[6]	Qihang Zhao, Longchang Tang, Peng Jiao. Construction of Spiro Skeletons in 2,2',3,3'-Tetrahydro-1,1'- spirobi[1H-indene]-7,7'-diol (SPINOL) and Analogues [J]. Chinese Journal of Organic Chemistry, 2021, 41(9): 3400-3413.
[7]	Jiejun Huang, Rongrong Qian, Shuang Wang, Hong'en Cao. Polyselenide-Catalyzed Cyclohexene Oxidation to Produce 1,2-Cyclohexanediol [J]. Chinese Journal of Organic Chemistry, 2021, 41(4): 1639-1645.
[8]	Shi Zhan, Nie Kerui, Liu Chang, Zhang Mingzhi, Zhang Weihua. Biological Activities of 3-(5-Oxazolyl)indole Natural Products and Advances on Synthesis of Its Derivatives [J]. Chinese Journal of Organic Chemistry, 2020, 40(2): 327-338.
[9]	Ju Chenyang, Wu Zhengxing, Li Yunyi, Zhang Wanbin. Palladium(II)-Catalyzed Aerobic 1,2-Diacetoxylation of Conjugated Dienes [J]. Chinese Journal of Organic Chemistry, 2020, 40(11): 3925-3933.
[10]	Xu Huanji, Li Zheming, Wu Yunqiu, Luo Di, Qiu Li, Xie Jizhao, Li Xuehua. Advances on Synthesis of Flavonoid Glycosides [J]. Chin. J. Org. Chem., 2019, 39(7): 1875-1890.
[11]	Liu Liangyan, Feng Tao, Li Zhenghui, Liu Jikai. Four New 2,5-Disubstituted Furan Vicinal Diols from the Fungus Ceriporia alachuana [J]. Chin. J. Org. Chem., 2017, 37(6): 1577-1581.
[12]	Tong Qing, Gao Qiang, Xu Bolian, Yu Lei, Fan Yining. Pt/WO₃/ZrO₂-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1,3-Propanediol [J]. Chin. J. Org. Chem., 2017, 37(3): 753-758.
[13]	Sun Huimin, Hu Chen, Hao Zhiming, Zuo Yajie, Wang Tianchi, Zhong Chongmin. Imidazolinium Perrhenate-Catalyzed Deoxydehydration ofVicinal Diols to Alkenes [J]. Chin. J. Org. Chem., 2015, 35(9): 1904-1909.
[14]	Niu Shaoxiong, Tang Zhichao, Liu Chang, Wang Tianlin, You Qidong, Xiang Hua. An Improved Synthesis of 6-Arylindenoisoquinoline Derivatives [J]. Chin. J. Org. Chem., 2015, 35(10): 2150-2156.
[15]	Wang Wenli, He Qing, Ding Ru, He Yun, Zhang Zunting. Synthesis of 1-Hydroxy-2-phenyltriphenylene Derivatives by Three-Step Condensation [J]. Chin. J. Org. Chem., 2014, 34(9): 1875-1880.