Study on the Synthetic Technology of Nitrofulleropyrrolidine

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (02): 276-278. Previous Articles Next Articles

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含能富勒烯吡咯烷衍生物的合成及工艺研究

彭汝芳*^,a，金波^a，曹葵^a，舒远杰^b，楚士晋^a

(^a西南科技大学材料科学与工程学院绵阳 621010)
(^b中国工程物理研究院化工材料研究所绵阳 621900)

收稿日期:2005-12-23 修回日期:2006-07-10 发布日期:2007-01-30
通讯作者: 彭汝芳

Study on the Synthetic Technology of Nitrofulleropyrrolidine

PENG, Ru-Fang*^,a JIN, Bo^a CAO, Kui^a SHU, Yuan-Jie^b CHU, Shi-Jin^a

(^a School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010)
(^b Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900)

Received:2005-12-23 Revised:2006-07-10 Published:2007-01-30
Contact: PENG, Ru-Fang

Abstract

A new nitrofulleropyrrolidine derivative 1 was prepared by the Prato reaction, and the effects of ratios of raw materials, temperature and reaction time on the reaction were studied. The optimum synthetic technology conditions with 94.8% yield (based on consumed C₆₀) are: 1∶1∶2 of molar ratio of C₆₀, m-nitrobenzaldehyde and N-methylglycine, 100 ℃ of reaction temperature, 16 h of reaction time. The structure of product 1 was characterized by UV-Vis, FT-IR, ¹H NMR,¹³C NMR and MS spectra.

Key words: C₆₀, energeticfullerene, synthetic technology, m-nitrobenzaldehyde, N-methylglycine

Cite this article

PENG, Ru-Fang*^,a JIN, Bo^a CAO, Kui^a SHU, Yuan-Jie^b CHU, Shi-Jin^a. Study on the Synthetic Technology of Nitrofulleropyrrolidine[J]. Chin. J. Org. Chem., 2007, 27(02): 276-278.

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含能富勒烯吡咯烷衍生物的合成及工艺研究

Study on the Synthetic Technology of Nitrofulleropyrrolidine

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