One-pot synthesis of 3-(5’-subsituted-benzoxazol-2’-yl)-7-diethylamino-chromen-2-one catalyzed with ZSM-5

doi:10.6023/cjoc1111173

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (05): 930-933.DOI: 10.6023/cjoc1111173 Previous Articles Next Articles

Notes

ZSM-5 催化一锅法合成3-(5′-取代-2’-苯并噁唑基)-7-二乙基氨基-2H-1-苯并吡喃-2-酮

蒋绍亮^a, 韩亮^b

a 浙江工业大学药学院, 浙江工业大学工业催化学科杭州 310032;
b 浙江工业大学化材学院, 杭州 310032

收稿日期:2012-01-29 修回日期:2012-03-05 发布日期:2012-03-31
通讯作者: 韩亮 E-mail:hanliang814@163.com
基金资助:
浙江省自然科学基金(No. Y12B030037)和浙江省教育厅基金(No. Y201018410)资助项目.

One-pot synthesis of 3-(5’-subsituted-benzoxazol-2’-yl)-7-diethylamino-chromen-2-one catalyzed with ZSM-5

Jiang Shaoliang^a, Han Liang^b

a College of Pharmaceutical Science, Industial Catalysis Subjects, Zhejiang University of Technology, Hangzhou 310032;
b College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032

Received:2012-01-29 Revised:2012-03-05 Published:2012-03-31
Supported by:
Project supported by the Natural Science Foundation of Zhejiang Province (No. Y12B030037) and the Foundation of Department of Education of Zhejiang Province (No. Y201018410).

3-(5’-subsituted-benzooxazol-2’-yl)-7-diethylamino-chromen-2-ones were prepared by one pot three-component reaction of 4-diethylaminosalicylaldehydes, ethyl cyanoacetate and o-aminophenols in refluxing n-butanol catalyzed with ZSM-5. This method has advantages of better yields and more environment-friendly process compared with that catalyzed with liquid catalysts.

Key words: Coumarin, solid acid catalyst, One-pot synthesis, ZSM-5 zeolite

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Jiang Shaoliang, Han Liang. One-pot synthesis of 3-(5’-subsituted-benzoxazol-2’-yl)-7-diethylamino-chromen-2-one catalyzed with ZSM-5[J]. Chin. J. Org. Chem., 2012, 32(05): 930-933.

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ZSM-5 催化一锅法合成3-(5′-取代-2’-苯并噁唑基)-7-二乙基氨基-2H-1-苯并吡喃-2-酮

One-pot synthesis of 3-(5’-subsituted-benzoxazol-2’-yl)-7-diethylamino-chromen-2-one catalyzed with ZSM-5

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