Synthesis and Characterization of Graphene Oxide Supported Schiff Base Palladium Catalyst and Its Catalytic Performance to Suzuki Reaction

doi:10.6023/cjoc201312022

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (8): 1630-1638.DOI: 10.6023/cjoc201312022 Previous Articles Next Articles

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氧化石墨烯负载席夫碱钯催化剂的合成、表征及对Suzuki反应催化性能的研究

袁定重^a,b, 陈碧波^b

a 核资源与环境省部共建国家重点实验室培育基地东华理工大学南昌 330013;
b 东华理工大学材料系南昌 330013

收稿日期:2014-12-18 修回日期:2014-04-08 发布日期:2014-04-16
通讯作者: 袁定重 E-mail:ydz3214@126.com
基金资助:
国家自然科学基金（Nos.21004009，21264001）、江西省自然科学基金（No.20114BAB213011）、江西省教育厅基金（No.GJJ13447）、东华理工大学博士科研启动基金（No.DHBK1010）资助项目.

Synthesis and Characterization of Graphene Oxide Supported Schiff Base Palladium Catalyst and Its Catalytic Performance to Suzuki Reaction

Yuan Dingzhong^a,b, Chen Bibo^b

a State Key Laboratory Breeding Base of Nuclear Resources and Environment, East China Institute of Technology, Nanchang 330013;
b Department of Materials Science and Engineering, East China Institute of Technology, Nanchang 330013

Received:2014-12-18 Revised:2014-04-08 Published:2014-04-16
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21004009, 21264001), the Natural Science Foundation of Jiangxi Province (No. 20114BAB213011), the Science and Technology Project of Jiangxi Provincial Department of Education (No. GJJ13447) and the Doctoral Scientific Research Foundation of East China of Technology (No. DHBK1010).

Graphene oxide prepared by modified Hummers method was used to immobilize Shiff base palladium complex. The novel supported catalyst was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray potoelectron sectroscopy (XPS), termogravity (TGA) and furier transform infrared spectrometer (FTIR). The supported palladium compound is an efficient catalyst for Suzuki reaction of aryl halides with phenylboronic acid to substituted trans-cinnamic acid or trans-stilbene at atmospheric condition in aqueous media, and the catalyst could be steadily dispersed in the reaction mixture. The supported catalyst still remains high activity after repeatedly five times.

Key words: graphene oxide, Schiff base, Suzuki reaction, palladium catalyst

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Yuan Dingzhong, Chen Bibo. Synthesis and Characterization of Graphene Oxide Supported Schiff Base Palladium Catalyst and Its Catalytic Performance to Suzuki Reaction[J]. Chin. J. Org. Chem., 2014, 34(8): 1630-1638.

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氧化石墨烯负载席夫碱钯催化剂的合成、表征及对Suzuki反应催化性能的研究

Synthesis and Characterization of Graphene Oxide Supported Schiff Base Palladium Catalyst and Its Catalytic Performance to Suzuki Reaction

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