Recent Advances in Aryne Double Bond Insertion

doi:10.6023/cjoc201411041

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (4): 770-780.DOI: 10.6023/cjoc201411041 Previous Articles Next Articles

REVIEW

苯炔对双键插入反应的研究进展

吴春蕊^a, 杨玉坡^b, 史峰^a

a 河南大学河南省天然药物与免疫工程重点实验室开封 475004;
b 青岛科技大学化学与分子工程学院青岛 266042

收稿日期:2014-11-26 修回日期:2014-12-15 发布日期:2015-01-09
通讯作者: 史峰 E-mail:fshi@henu.edu.cn
基金资助:
国家自然科学基金(No. 21002021)和河南省高校科技创新人才支持计划基金(No. 13HASTIT010)资助项目.

Recent Advances in Aryne Double Bond Insertion

Wu Chunrui^a, Yang Yupo^b, Shi Feng^a

a Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province, Henan University, Kaifeng 475004;
b College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042

Received:2014-11-26 Revised:2014-12-15 Published:2015-01-09
Supported by:
Project supported by National Natural Science Foundation of China (No. 21002021) and the Program for Science & Technology Innovation Talents in Universities of Henan Province (No. 13HASTIT010).

Aryne double bond insertion generates an ortho-quinomethide-typed intermediate, which, like aryne itself, is one of the most important reactive intermediates in organic reactions. This review summarizes recent advances in this field and the potential applications in synthetic organic chemistry, with a focus on the reaction mechanism, as well as the structure and reactivity of the ortho-quinomethide intermediates.

Key words: aryne, ortho-quinomethide, reactive intermediate, pericyclic reaction, tandem reaction

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Wu Chunrui, Yang Yupo, Shi Feng. Recent Advances in Aryne Double Bond Insertion[J]. Chin. J. Org. Chem., 2015, 35(4): 770-780.

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苯炔对双键插入反应的研究进展

Recent Advances in Aryne Double Bond Insertion

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