Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (8): 2124-2130.DOI: 10.6023/cjoc201612054 Previous Articles     Next Articles

Notes

钯/碳催化三唑导向C—H键活化芳基化

谢晓强, 邢运哲, 张国富, 丁成荣   

  1. 浙江工业大学化学工程学院 杭州 310014
  • 收稿日期:2016-12-22 修回日期:2017-04-03 发布日期:2017-04-21
  • 通讯作者: 丁成荣 E-mail:dingcr@zjut.edu.cn
  • 基金资助:

    国家自然科学基金(No.20702051)、浙江省自然科学基金(No.LY13B020017)、浙江省科技重点创新团队(No.2010R50018)资助项目

Pd/C Catalyzed C—H Arylation with Click-Triazoles as Removable Directing Group

Xie Xiaoqiang, Xing Yunzhe, Zhang Guofu, Ding Chengrong   

  1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2016-12-22 Revised:2017-04-03 Published:2017-04-21
  • Contact: 10.6023/cjoc201612054 E-mail:dingcr@zjut.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 20702051), the Natural Science Foundation of Zhejiang Province (No. LY13B020017) and the Key Innovation Team of Science and Technology in Zhejiang Province (No. 2010R50018).

A novel protocol for Pd/C catalyzed C(sp2)—H arylation of benzamides with good functional group compatibility under silver-free conditions by using click-triazoles as a removable directing group has been first developed.

Key words: Pd/C, click-triazoles, arylation, C—H bond activation