Cu-Catalyzed Direct Arylation of Benzothiazoles with Diaryliodonium Salts

doi:10.6023/cjoc202002042

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (8): 2476-2482.DOI: 10.6023/cjoc202002042 Previous Articles Next Articles

铜催化苯并噻唑与二芳基碘鎓盐的芳基化反应

李怀贵, 杨澎, 许峥, 杜正银, 傅颖

西北师范大学化学化工学院兰州 730070

收稿日期:2020-02-29 修回日期:2020-05-10 发布日期:2020-05-20
通讯作者: 杜正银, 傅颖 E-mail:clinton_du@126.com;fu_yingmail@126.com
基金资助:
国家自然科学基金（Nos.21262028，21762039，21762040）资助项目.

Cu-Catalyzed Direct Arylation of Benzothiazoles with Diaryliodonium Salts

Li Huaigui, Yang Peng, Xu Zheng, Du Zhengyin, Fu Ying

College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received:2020-02-29 Revised:2020-05-10 Published:2020-05-20
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21262028, 21762039, 21762040).

1. cjoc202002042辅助材料.pdf(889KB)

Abstract

Diaryliodonium salts have low toxicity and good stability, and their mediated reactions often have advantages of mild reaction conditions and high selectivity. They have received extensive attention and have been widely used as arylating agents in organic synthesis. A simple and efficient method for the synthesis of 2-arylbenzothiazole derivatives via copper-catalyzed C-H direct arylation of benzothiazoles with diaryliodonium salts as electrophilic arylating reagents was developed. This method shows wide range of substrates, good group tolerance, simple operation and high product yields.

Key words: benzothiazole, arylation, diaryliodonium salt, cross coupling, C-H activation

Cite this article

Li Huaigui, Yang Peng, Xu Zheng, Du Zhengyin, Fu Ying. Cu-Catalyzed Direct Arylation of Benzothiazoles with Diaryliodonium Salts[J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2476-2482.

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铜催化苯并噻唑与二芳基碘鎓盐的芳基化反应

Cu-Catalyzed Direct Arylation of Benzothiazoles with Diaryliodonium Salts

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