Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions with Allylic Esters

doi:10.6023/cjoc201704034

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (12): 3039-3059.DOI: 10.6023/cjoc201704034 Previous Articles Next Articles

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铱催化烯丙基酯的不对称烯丙基取代反应研究进展

邓颖颍, 杨文, 杨新, 杨定乔

华南师范大学化学与环境学院教育部环境理论化学重点实验室广州 510006

收稿日期:2017-04-19 修回日期:2017-06-21 发布日期:2017-08-11
通讯作者: 杨定乔 E-mail:yangdq@scnu.edu.cn
基金资助:
国家自然科学基金（Nos.21172081，21372090）、广东省自然科学基金重点（No.S2013020013091）和广州市科技计划（No.201510010054）资助项目.

Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions with Allylic Esters

Deng Yingying, Yang Wen, Yang Xin, Yang Dingqiao

Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Received:2017-04-19 Revised:2017-06-21 Published:2017-08-11
Contact: 10.6023/cjoc201704034 E-mail:yangdq@scnu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21172081, 21372090), the Natural Science Foundation of Guangdong Province (No. S2013020013091) and the Science and Technology Plan Projects of Guangzhou City (No. 201510010054).

Iridium-catalyzed asymmetric allylic substitution reaction is one of the most important methods for the synthesis of chiral compounds. The recent research progress in iridium-catalyzed asymmetric allylic substitution reactions of allylic ester and its derivatives is reviewed with focus on the influences of the iridium catalysts, the substrate structures of allylic ester and its derivatives, the type of nucleophiles, the effects of solvents and additives on asymmetric substitution reaction. Moreover, the possible mechanisms are also discussed in this review.

Key words: iridium catalyst, allylic esters, asymmetric allylic substitution, nucleophile, recent research progress

Cite this article

Deng Yingying, Yang Wen, Yang Xin, Yang Dingqiao. Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions with Allylic Esters[J]. Chin. J. Org. Chem., 2017, 37(12): 3039-3059.

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铱催化烯丙基酯的不对称烯丙基取代反应研究进展

Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions with Allylic Esters

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