Carbolong Complexes as Photothermal Materials

doi:10.6023/cjoc201901048

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (6): 1743-1752.DOI: 10.6023/cjoc201901048 Previous Articles Next Articles

Special Issue: 金属有机化学

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具有光热性能的碳龙配合物材料

吴凡^a, 黄文超^c, 卓凯玥^b, 华煜晖^b, 林剑锋^b, 何国梅^a, 陈江溪^a, 聂立铭^c, 夏海平^b

a 厦门大学材料学院材料科学与工程系厦门 361005;
b 厦门大学化学化工学院化学系厦门 361005;
c 厦门大学公共卫生学院分子影像暨转化医学研究中心分子疫苗学和分子诊断学国家重点实验室厦门 361102

收稿日期:2019-01-28 修回日期:2019-03-13 发布日期:2019-03-21
通讯作者: 何国梅, 聂立铭, 夏海平 E-mail:gmhe@xmu.edu.cn;nielm@xmu.edu.cn;hpxia@xmu.edu.cn
基金资助:
国家自然科学基金（Nos.21302158，U1705254，21490573）资助项目.

Carbolong Complexes as Photothermal Materials

Wu Fan^a, Huang Wenchao^c, Zhuo Kaiyue^b, Hua Yuhui^b, Lin Jianfeng^b, He Guomei^a, Chen Jiangxi^a, Nie Liming^c, Xia Haiping^b

a Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005;
b Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005;
c State Key Laboratory of Molecular Vaccinology and Molecular Diagnosis, Center for Molecular Imaging and Translational Medicine, School of Public Health, Xiamen University, Xiamen 361102

Received:2019-01-28 Revised:2019-03-13 Published:2019-03-21
Contact: 10.6023/cjoc201901048 E-mail:gmhe@xmu.edu.cn;nielm@xmu.edu.cn;hpxia@xmu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21302158, U1705254, 21490573).

1. Carbolong Complexes as Photothermal Materials.PDF(5100KB)

Abstract

A series of photothermal cyclobutaosmapentalenes with conjugated groups attached to the metallacycle were synthesized from the reaction of OsCl₂(PPh₃)₃ with an organic multiyne and PPh₃, followed by a[2+2] cycloaddition with terminal alkynes. These highly conjugated metallacycles showed broad UV-Vis absorption and good photothermal efficiency. These easily synthesized metallacycles represent a type of new photothermal material.

Key words: organometallics, metallacycle, photothermal

Cite this article

Wu Fan, Huang Wenchao, Zhuo Kaiyue, Hua Yuhui, Lin Jianfeng, He Guomei, Chen Jiangxi, Nie Liming, Xia Haiping. Carbolong Complexes as Photothermal Materials[J]. Chin. J. Org. Chem., 2019, 39(6): 1743-1752.

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具有光热性能的碳龙配合物材料

Carbolong Complexes as Photothermal Materials

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