Advances in the Synthesis of Phosphorothioate and Phosphinothioate

doi:10.6023/cjoc202104002

Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (8): 2964-2973.DOI: 10.6023/cjoc202104002 Previous Articles Next Articles

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硫代磷(膦)酸酯的合成研究进展

刘春琪^a, 王莉贤^a, 张兴华^a^,^b^,^*()

a 上海应用技术大学化学与环境工程学院上海 201418
b 宁波大学新药技术研究院浙江宁波 315211

收稿日期:2021-04-01 修回日期:2021-05-06 发布日期:2021-05-25
通讯作者: 张兴华
基金资助:
国家自然科学基金(21871182)

Advances in the Synthesis of Phosphorothioate and Phosphinothioate

Chunqi Liu^a, Lixian Wang^a, Xinghua Zhang^a^,^b()

a School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418
b Institute of Drug Discovery Technology, Ningbo University, Ningbo, Zhengjiang 315211

Received:2021-04-01 Revised:2021-05-06 Published:2021-05-25
Contact: Xinghua Zhang
Supported by:
National Natural Science Foundation of China(21871182)

Cite this article

Chunqi Liu, Lixian Wang, Xinghua Zhang. Advances in the Synthesis of Phosphorothioate and Phosphinothioate[J]. Chinese Journal of Organic Chemistry, 2021, 41(8): 2964-2973.

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Fig. & Tab. 10

Figure 1. Application of phosphorothioate in medicine and pesticides

Scheme 2. Cs2CO3 promoted coupling reaction

Scheme 3. KI/TBPB promotes the preparation of thiophosphonate compounds

Scheme 4. DMSO promoted coupling reaction

Scheme 5. Photocatalytic cross-coupling reaction to construct P(O)—S bond

Scheme 6. Direct coupling of P(O)—H to disulfides

Scheme 7. Coupling reaction of CsOH catalyzed hydrogen phosphite with disulfide

Scheme 8. Cu-catalyzed coupling of arylsulfonyl chloride with alkoxy phosphite to prepare S-aryl thiophosphonates

Scheme 9. Metal- and oxidant-free P(O)—S bond construction via direct coupling of P(O)—H with sulfinic acids

Scheme 10. Preparation of sulfur (selenium) phosphonate by Sn catalysis

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硫代磷(膦)酸酯的合成研究进展

Advances in the Synthesis of Phosphorothioate and Phosphinothioate

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