Study on the Heck Arylation Reaction Catalyzed by Chitosan-immobilized Palladium(0) Complex

Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (1): 59-62. Previous Articles Next Articles

壳聚糖钯(0)配合物催化Heck芳基化反应研究

刘蒲^*, 王岚, 李利民, 王向宇

郑州大学化学系郑州 450052

收稿日期:2003-03-13 修回日期:2003-06-23 接受日期:2003-08-07 发布日期:2022-09-21
基金资助:
2001年度河南省高校青年骨干教师资助项目.

Study on the Heck Arylation Reaction Catalyzed by Chitosan-immobilized Palladium(0) Complex

LIU Pu^*, WANG Lan, LI Li-Min, WANG Xiang-Yu

Department of Chemistry, Zhengzhou University, Zhengzhou 450052

Received:2003-03-13 Revised:2003-06-23 Accepted:2003-08-07 Published:2022-09-21
Contact: *E-mail: liupu@zzu.edu.cn

Abstract

Using the natural polymer-chitosan as supporter, yellow powder of chitosan-immobilized palladium(II) chloride which was prepared bytreating chitosan with palladium chloride in ethanol at room temperature was refluxed in ethanol to produce chitosan-immobilized palladium(0) catalyst. Its catalytic performance for Heck arylation of acrylic acid with iodobenzene shows that the catalyst has high catalytic activity and regioselectivity for the synthesis of trans-phenylacrylic acid. The catalyst can be recovered by filtrationand washing with solvent, and reused for many times. The Heck arylation reactions of other substrates catalyzed by chitosan-immobilized palladium(0) complex were also investigated.

Key words: chitosan, palladium complex, trans-phenylacrylic acid, Heck arylation reaction

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LIU Pu, WANG Lan, LI Li-Min, WANG Xiang-Yu. Study on the Heck Arylation Reaction Catalyzed by Chitosan-immobilized Palladium(0) Complex[J]. Chinese Journal of Organic Chemistry, 2004, 24(1): 59-62.

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壳聚糖钯(0)配合物催化Heck芳基化反应研究

Study on the Heck Arylation Reaction Catalyzed by Chitosan-immobilized Palladium(0) Complex

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