Application of Biobased Catalysts in Chemical Conversion of CO2

doi:10.6023/cjoc202312011

Abstract

CO₂ is the most abundant C1 platform compound on earth, characterized by non-toxicity, renewability, chemical stability, and availability. Therefore, it is of great significance to convert CO₂ into high value-added chemicals through chemical conversion. Due to the high thermodynamic stability and kinetic inertness of CO₂, most chemical conversion reactions require the use of high-efficiency catalysts. So far, various catalytic systems have been developed, such as porous carbon, ionic liquids (ILs), covalent organic frameworks (COFs), porous organic polymers (POPs), and metal organic frameworks (MOFs). Although these catalysts have high catalytic activity, they also have many drawbacks, namely, the source of raw materials is not wide, and most of these raw materials are not renewable, and the preparation process of these catalysts is not green. Therefore, it is particularly important to prepare renewable catalysts using small natural molecules or natural polymers as raw materials. The research progress of catalytic systems containing natural products, such as amino acids, choline derivatives, cellulose, chitosan, lignin, etc., is summarized in the preparation of high value-added chemicals from CO₂.

Key words: biobased catalysts, CO₂, chemical conversion, green synthesis

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Jinbin Gao, Yingqi Lu, Hui Zhang, Lizhu Gao, Xingquan Xiong. Application of Biobased Catalysts in Chemical Conversion of CO₂[J]. Chinese Journal of Organic Chemistry, 2024, 44(9): 2732-2741.

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Fig. & Tab. 16

Scheme 1. Synthesis of various organic compounds using CO2 as raw material

Scheme 2. Microwave-assisted one-pot synthesis of AAILs

Figure 1. Structures of AAILs modified by N heterocyclic cations

Scheme 3. Synthesis of AAILs modified by ether-functionalized imidazole cations

Figure 2. Structures of DESs modified by different organic acids

Figure 3. Structures of DESs with bio-based organic acids as HBD

Figure 4. Synthesis of seaweed acid-based catalyst AA-950[41]

Figure 5. Synthesis of cedar biomass-based N-doped electrocatalyst CB-NGC[43]

Scheme 4. Synthesis of bean dregs-based N-doped carbon materials[45]

Scheme 5. Synthesis of quaternary ammonium cellulose catalysts mQCs

Scheme 6. Synthesis of rice husk cellulose-based poly(ionic liquids)

Scheme 7. Kraft lignin and melanin-based nanoparticles catalyzed conversion of CO2 to cyclic carbonates

Scheme 8. Synthesis of CS and phytic acid-based MOHs

Figure 6. Structures of CS-based catalysts

Scheme 9. Synthesis of gallic acid-based porous polymers Ag/GA-azo-POP

Figure 7. Structure of MFM-KUST catalysts

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生物质基催化剂在CO₂化学转化中的应用

Application of Biobased Catalysts in Chemical Conversion of CO₂

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生物质基催化剂在CO2化学转化中的应用