Recent Advances in Photocatalytic Carboxylation with CO2 via σ-Bond Cleavage

doi:10.6023/cjoc202206003

Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (12): 4257-4274.DOI: 10.6023/cjoc202206003 Previous Articles Next Articles

Special Issue: 自由基化学专辑

REVIEWS

光催化CO₂参与的σ键断裂羧基化反应研究进展

窦谦^a^,^b, 汪太民^a^,^*(), 李嗣锋^a, 房丽晶^a^,^b, 翟宏斌^a^,^c, 程斌^a^,^*()

a 深圳职业技术学院海洋生物医药研究院/博士后创新实践基地广东深圳 518055
b 中国科学院深圳先进技术研究院生物医药与技术研究所广东深圳 518055
c 北京大学深圳研究生院肿瘤化学基因组学国家重点实验室广东深圳 518055

收稿日期:2022-06-02 修回日期:2022-07-13 发布日期:2022-08-10
通讯作者: 汪太民, 程斌
基金资助:
广东省教育厅产教融合创新平台(2021CJPT014); 广东省教育厅创新团队(2022KCXTD054); 深圳职业技术学院深圳市高端人才科研启动(6022310047k); 深圳市科技创新委员会(JSGG20201103153800002); 深圳市科技创新委员会(GJHZ20200731095412037); 深圳市科技创新委员会(JCYJ20200109141808025); 深圳职业技术学院博士后基金(6021330006K)

Recent Advances in Photocatalytic Carboxylation with CO₂ via σ-Bond Cleavage

Qian Dou^a^,^b, Taimin Wang^a(), Sifeng Li^a, Lijing Fang^a^,^b, Hongbin Zhai^a^,^c, Bin Cheng^a()

a Institute of Marine Biomedicine, Postdoctoral Innovation Practice Base, Shenzhen Polytechnic, Shenzhen, Guangdong 518055
b Institute of Biomedicine and Biotechnology, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, Guangdong 518055
c State Key Laboratory of Chemical Oncogenomics, Peking University Shenzhen Graduate School, Shenzhen, Guangdong 518055

Received:2022-06-02 Revised:2022-07-13 Published:2022-08-10
Contact: Taimin Wang, Bin Cheng
Supported by:
Innovation Platform for the Integration of Production and Education of Guangdong Provincial Education Department(2021CJPT014); Innovation Team of Guangdong Education Department(2022KCXTD054); Scientific Research Startup Fund for Shenzhen High-Caliber Personnel of Shenzhen Polytechnic(6022310047k); Shenzhen Science and Technology Innovation Committee(JSGG20201103153800002); Shenzhen Science and Technology Innovation Committee(GJHZ20200731095412037); Shenzhen Science and Technology Innovation Committee(JCYJ20200109141808025); Post-doctoral Foundation Project of Shenzhen Polytechnic(6021330006K)

Carbon dioxide (CO₂), as the main components of greenhouse gases, is one of the most abundant carbon sources at present. In organic chemistry, CO₂ is often used as C1 synthon to synthesize carboxylic acids by constructing C—C bond. Transition metal catalysis has developed as a powerful tool for the conversion and utilization of CO₂. In order to achieve the strategic goal of “double carbon”, it is of great significance to develop green and sustainable CO₂ conversion and utilization technology combined with contemporary hot topics in the field of organic chemistry. In recent years, the development of photocatalytic synthesis technology provied a new opportunity for the conversion and utilization of CO₂. The bond breaking of C—H bond, C—O bond, C—N and C—X bond and carboxylation reactions with CO₂ by photocatalysis strategy were systematically described.

Key words: photocatalysis, CO₂, σ-bond cleavage, carboxylation

Cite this article

Qian Dou, Taimin Wang, Sifeng Li, Lijing Fang, Hongbin Zhai, Bin Cheng. Recent Advances in Photocatalytic Carboxylation with CO₂ via σ-Bond Cleavage[J]. Chinese Journal of Organic Chemistry, 2022, 42(12): 4257-4274.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 22

Scheme 1. Light-driven C(sp3)—H bonds carboxylation of o?alkylphenyl ketones with CO2

Scheme 2. Light/copper dual catalyzed carboxylation of allylic C(sp3)—H bonds of alkenes with CO2

Scheme 3. Photocatalyzed C(sp3)—H bonds carboxylation of amines with CO2

Scheme 4. Light/nickel dual catalyzed carboxylation of benzyl C(sp3)—H bonds with CO2

Scheme 5. Organic photosensitizer catalyzed carboxylation of benzyl C(sp3)—H bonds with CO2

Scheme 6. Light/nickel dual catalyzed remote C(sp3)—H bonds carboxylation of alkyl bromides with CO2

Scheme 7. Visible-light photoredox-catalyzed remote C(sp3)—H bonds carboxylation of unactivated alkenes with CO2

Scheme 8. Visible-light photoredox catalyzed aryl C—H bonds carboxylation with CO2

Scheme 9. Organic photosensitizer catalyzed aryl C—H bonds carboxylation with CO2

Scheme 10. Visible-light photoredox/nickel dual catalyzed aryl C—O bonds carboxylation with CO2

Scheme 11. Visible-light photoredox/palladium dual catalyzed aryl and alkenyl C—O bonds carboxylation with CO2

Scheme 12. Visible-light photoredox/palladium dual catalyzed aryl C—O bonds carboxylation with CO2

Scheme 13. Visible-light photoredox/palladium dual catalyzed benzyl C—O bonds carboxylation with CO2

Scheme 14. Organic photosensitizer catalyzed benzyl C—O bonds carboxylation with CO2

Scheme 15. Visible-light photoredox catalyzed C—O bonds carboxylation of benzyl alcohol with CO2

Scheme 16. Visible-light photoredox/nickel dual catalyzed allylic C—O bonds carboxylation with CO2

Scheme 17. Visible-light photoredox catalyzed C—N bonds carboxylation of tetraalkyl ammonium salts with CO2

Scheme 18. Visible-light photoredox/palladium dual catalyzed aryl C—Br/Cl bonds carboxylation with CO2

Scheme 19. Visible-light photoredox/nickel dual catalyzed aryl and alkyl C—Br bonds carboxylation with CO2

Scheme 20. Organic photosensitizer catalyzed benzyl C—X bonds carboxylation with CO2

Scheme 21. Visible-light photoredox/palladium dual catalyzed alkenyl C—F bonds carboxylation with CO2

Scheme 22. Visible-light photoredox catalyzed alkyl C—F bonds carboxylation with CO2

References 34

[1]	(a) Sakakura, T.; Choi, J.-C.; Yasuda, H. Chem. Rev. 2007, 107, 2365. doi: 10.1021/cr068357u pmid: 31015931
	(b) He, M.; Sun, Y.; Han, B. Angew. Chem., nt. Ed. 2013, 52, 9620. pmid: 31015931
	(c) Yang, Y.; Lee, J.-W. Chem. Sci. 2019, 10, 3905. doi: 10.1039/c8sc05539d pmid: 31015931
	(d) Ye, J.-H.; Ju, T.; Huang, H.; Liao, L.-L.; Yu, D.-G. Acc. Chem. Res. 2021, 54, 2518. doi: 10.1021/acs.accounts.1c00135 pmid: 31015931
	(e) Ran, C.-K.; Liao, L.-L.; Gao, T.-Y.; Gui, Y.-Y.; Yu, D.-G. Curr. Opin. Green Sustainable Chem. 2021, 32, 100525. pmid: 31015931
[2]	(a) Maag, H. Prodrugs: Challenges and Rewards Part 1, Vol. 5, Eds.: Stella, J.; Borchardt, R.T.; Hageman, M. J.; Oliyai, R.; Maag, H.; Tilley, J. W., Springer, New York, 2007, p. 703.
	(b) Gooßen, L. J.; Rodríguez, N.; Gooßen, K. Angew. Chem., nt. Ed. 2008, 47, 3100.
[3]	Kobayashi, K.; Kondo, Y. Org. Lett. 2009, 11, 2035. doi: 10.1021/ol900528h pmid: 19338291
[4]	(a) Cokoja, M.; Bruckmeier, C.; Rieger, B.; Herrmann, W. A.; Kühn, F. E. Angew. Chem., nt. Ed. 2011, 50, 8510. pmid: 21387036
	(b) Huang, K.; Sun, C.-L.; Shi, Z.-J. Chem. Soc. Rev. 2011, 40, 2435. doi: 10.1039/c0cs00129e pmid: 21387036
	(c) Yu, D.; Teong, S. P.; Zhang, Y. Coord. Chem. Rev. 2015, 293, 279. pmid: 21387036
	(d) Tortajada, A.; Juliá-Hernández, F.; Börjesson, M.; Moragas, T.; Martin, R. Angew. Chem., nt. Ed. 2018, 57, 15948. pmid: 21387036
[5]	(a) Prier, C. K.; Rankic, D. A.; MacMillan, D. W. C. Chem. Rev. 2013, 113, 5322. doi: 10.1021/cr300503r pmid: 34350919
	(b) Staveness, D.; Bosque, I.; Stephenson, C. R. J. Acc. Chem. Res. 2016, 49, 2295. doi: 10.1021/acs.accounts.6b00270 pmid: 34350919
	(c) Hopkinson, M. N.; Tlahuext-Aca, A.; Glorius, F. Acc. Chem. Res. 2016, 49, 2261. doi: 10.1021/acs.accounts.6b00351 pmid: 34350919
	(d) Shaw, M. H.; Twilton, J.; MacMillan, D. W. C. J. Org. Chem. 2016, 81, 6898. doi: 10.1021/acs.joc.6b01449 pmid: 34350919
	(e) Douglas, J. J.; Sevrin, M. J.; Stephenson, C. R. J. Org. Process Res. Dev. 2016, 20, 1134. doi: 10.1021/acs.oprd.6b00125 pmid: 34350919
	(f) Lang, X.; Zhao, J.; Chen, X. Chem. Soc. Rev. 2016, 45, 3026. doi: 10.1039/C5CS00659G pmid: 34350919
	(g) Reed, N. L.; Yoon, T. P. Chem. Soc. Rev. 2021, 50, 2954. doi: 10.1039/D0CS00797H pmid: 34350919
	(h) Galliher, M. S.; Roldan, B. J.; Stephenson, C. R. J. Chem. Soc. Rev. 2021, 50, 10044. doi: 10.1039/d1cs00411e pmid: 34350919
[6]	(a) Gui, Y.-Y.; Zhou, W.-J.; Ye, J.-H.; Yu, D.-G. ChemSusChem 2017, 10, 1337. doi: 10.1002/cssc.201700205
	(b) Yeung, C. S. Angew. Chem., nt. Ed. 2019, 58, 5492.
	(c) Hou, J.; Li, J.-S.; Wu, J. Asian J. Org. Chem. 2018, 7, 1439. doi: 10.1002/ajoc.201800226
	(d) Zhang, Z.; Ye, J.-H.; Ju, T.; Liao, L.-L.; Huang, H.; Gui, Y.-Y.; Zhou, W.-J.; Yu, D.-G. ACS Catal. 2020, 10, 10871. doi: 10.1021/acscatal.0c03127
	(e) Zhang, G.; Cheng, Y.; Beller, M.; Chen, F. Adv. Synth. Catal. 2021, 363, 1583. doi: 10.1002/adsc.202001280
[7]	(a) Zhu, Q.; Wang, L.; Xia, C.; Liu, C. Chin. J. Org. Chem. 2016, 36, 2813. (in Chinese) doi: 10.6023/cjoc201606007
	( 朱庆, 王露, 夏春谷, 刘超, 有机化学, 2016, 36, 2813.) doi: 10.6023/cjoc201606007
	(b) Luo, J.; Larrosa, I. ChemSusChem 2017, 10, 3317. doi: 10.1002/cssc.201701058
[8]	Masuda, Y.; Ishida, N.; Murakami, M. J. Am. Chem. Soc. 2015, 137, 14063. doi: 10.1021/jacs.5b10032
[9]	Ishida, N.; Masuda, Y.; Uemoto, S.; Murakami, M. Chem.-Eur. J. 2016, 22, 6524. doi: 10.1002/chem.201600682 pmid: 26998686
[10]	Seo, H.; Katcher, M. H.; Jamison, T. F. Nat. Chem. 2017, 9, 453. doi: 10.1038/nchem.2690
[11]	Ishida, N.; Masuda, Y.; Imamura, Y.; Yamazaki, K.; Murakami, M. J. Am. Chem. Soc. 2019, 141, 19611. doi: 10.1021/jacs.9b12529 pmid: 31775498
[12]	Meng, Q.-Y.; Schirmer, T. E.; Berger, A. L.; Donabauer, K.; König, B. J. Am. Chem. Soc. 2019, 141, 11393. doi: 10.1021/jacs.9b05360
[13]	Sahoo, B.; Bellotti, P.; Juliá-Hernández, F.; Meng, Q.-Y.; Crespi, S.; König, B.; Martin, R. Chem.-Eur. J. 2019, 25, 9001. doi: 10.1002/chem.201902095
[14]	Song, L.; Fu, D.-M.; Chen, L.; Jiang, Y.-X.; Ye, J.-H.; Zhu, L.; Lan, Y.; Fu, Q.; Yu, D.-G. Angew. Chem., nt. Ed. 2020, 59, 21121.
[15]	Gao, Y.; Wang, H.; Chi, Z.; Yang, L.; Zhou, C.; Li, G. CCS Chem. 2021, 4, 1565. doi: 10.31635/ccschem.021.202100995
[16]	Yi, Y.; Xi, C. Chin. J. Catal. 2022, 43, 1652. doi: 10.1016/S1872-2067(21)63956-6
[17]	(a) Yu, D.-G.; Li, B.-J.; Shi, Z.-J. Acc. Chem. Res. 2010, 43, 1486. doi: 10.1021/ar100082d pmid: 25157613
	(b) Rosen, B. M.; Quasdorf, K. W.; Wilson, D. A.; Zhang, N.; Resmerita, A.-M.; Garg, N. K.; Percec, V. Chem. Rev. 2011, 111, 1346. doi: 10.1021/cr100259t pmid: 25157613
	(c) Su, B.; Cao, Z.-C.; Shi, Z.-J. Acc. Chem. Res. 2015, 48, 886. doi: 10.1021/ar500345f pmid: 25157613
	(d) Cornella, J.; Zarate, C.; Martin, R. Chem. Soc. Rev. 2014, 43, 8081. doi: 10.1039/c4cs00206g pmid: 25157613
	(e) Tobisu, M.; Chatani, N. Acc. Chem. Res. 2015, 48, 1717. doi: 10.1021/acs.accounts.5b00051 pmid: 25157613
	(f) Zeng, H.; Qiu, Z.; Domínguez-Huerta, A.; Hearne, Z.; Chen, Z.; Li, C.-J. ACS Catal. 2017, 7, 510. doi: 10.1021/acscatal.6b02964 pmid: 25157613
[18]	Meng, Q.-Y.; Wang, S.; König, B. Angew. Chem., nt. Ed. 2017, 56, 13426.
[19]	Shimomaki, K.; Nakajima, T.; Caner, J.; Toriumi, N.; Iwasawa, N. Org. Lett. 2019, 21, 4486. doi: 10.1021/acs.orglett.9b01340 pmid: 31180681
[20]	Bhunia, S. K.; Das, P.; Nandi, S.; Jana, R. Org. Lett. 2019, 21, 4632. doi: 10.1021/acs.orglett.9b01532 pmid: 31188621
[21]	Jin, Y.; Toriumi, N.; Iwasawa, N. ChemSusChem 2022, 15, e202102095.
[22]	Ran, C.-K.; Niu, Y.-N.; Song, L.; Wei, M.-K.; Cao, Y.-F.; Luo, S.-P.; Yu, Y.-M.; Liao, L.-L.; Yu, D.-G. ACS Catal. 2022, 12, 18. doi: 10.1021/acscatal.1c04921
[23]	Li, W.-D.; Wu, Y.; Li, S.-J.; Jiang, Y.-Q.; Li, Y.-L.; Lan, Y.; Xia, J.-B. J. Am. Chem. Soc. 2022, 144, 8551. doi: 10.1021/jacs.1c12463
[24]	Fan, Z.; Chen, S.; Zou, S.; Xi, C. ACS Catal. 2022, 12, 2781. doi: 10.1021/acscatal.2c00418
[25]	(a) Ouyang, K.; Hao, W.; Zhang, W.-X.; Xi, Z. Chem. Rev. 2015, 115, 12045. doi: 10.1021/acs.chemrev.5b00386
	(b) Wang, Q.; Su, Y.; Li, L.; Huang, H. Chem. Soc. Rev. 2016, 45, 1257. doi: 10.1039/C5CS00534E
	(c) Mo, F.; Qiu, D.; Zhang, Y.; Wang, J. Acc. Chem. Res. 2018, 51, 496. doi: 10.1021/acs.accounts.7b00566
	(d) Felpin, F.-X.; Sengupta, S. Chem. Soc. Rev. 2019, 48, 1150. doi: 10.1039/C8CS00453F
	(e) Mo, F.; Qiu, D.; Zhang, L.; Wang, J. Chem. Rev. 2021, 121, 5741. doi: 10.1021/acs.chemrev.0c01030
[26]	Wang, Z.-X.; Yang, B. Org. Biomol. Chem. 2020, 18, 1057. doi: 10.1039/C9OB02667C
[27]	Liao, L.-L.; Cao, G.-M.; Ye, J.-H.; Sun, G.-Q.; Zhou, W.-J.; Gui, Y.-Y.; Yan, S.-S.; Shen, G.; Yu, D.-G. J. Am. Chem. Soc. 2018, 140, 17338. doi: 10.1021/jacs.8b08792 pmid: 30518213
[28]	(a) Börjesson, M.; Moragas, T.; Gallego, D.; Martin, R. ACS Catal. 2016, 6, 6739. pmid: 27747133
	(b) Chen, Y.-G.; Xu, X.-T.; Zhang, K.; Li, Y.-Q.; Zhang, L.-P.; Fang, P.; Mei, T.-S. Synthesis 2018, 50, 35. doi: 10.1055/s-0036-1590908 pmid: 27747133
[29]	Shimomaki, K.; Murata, K.; Martin, R.; Iwasawa, N. J. Am. Chem. Soc. 2017, 139, 9467. doi: 10.1021/jacs.7b04838 pmid: 28657743
[30]	Jing, K.; Wei, M.-K.; Yan, S.-S.; Liao, L.-L.; Niu, Y.-N.; Luo, S.-P.; Yu, B.; Yu, D.-G. Chin. J. Catal. 2022, 43, 1667. doi: 10.1016/S1872-2067(21)63859-7
[31]	(a) Gillis, E. P.; Eastman, K. J.; Hill, M. D.; Donnelly, D. J.; Meanwell, N. A. J. Med. Chem. 2015, 58, 8315. doi: 10.1021/acs.jmedchem.5b00258 pmid: 26200936
	(b) Vivier, D.; Soussia, I. B.; Rodrigues, N.; Lolignier, S.; Devilliers, M.; Chatelain, F. C.; Prival, L.; Chapuy, E.; Bourdier, G.; Bennis, K.; Lesage, F.; Eschalier, A.; Busserolles, J.; Ducki, S. J. Med. Chem. 2017, 60, 1076. doi: 10.1021/acs.jmedchem.6b01285 pmid: 26200936
	(c) Jaeger, E. P.; Jurs, P. C.; Stouch, T. R. Eur. J. Med. Chem. 1993, 28, 275. doi: 10.1016/0223-5234(93)90145-5 pmid: 26200936
	(d) Cracowski, J.-M.; Montembault, V.; Bosc, D.; Améduri, B.; Odobel, F.; Fontaine, L. J. Polym. Sci.,Part A: Polym. Chem. 2009, 47, 1403. doi: 10.1002/pola.23249 pmid: 26200936
[32]	Zhu, C.; Zhang, Y.-F.; Liu, Z.-Y.; Zhou, L.; Liu, H.; Feng, C. Chem. Sci. 2019, 10, 6721. doi: 10.1039/C9SC01336A
[33]	Yan, S.-S.; Liu, S.-H.; Chen, L.; Bo, Z.-Y.; Jing, K.; Gao, T.-Y.; Yu, B.; Lan, Y.; Luo, S.-P.; Yu, D.-G. Chem. 2021, 7, 3099. doi: 10.1016/j.chempr.2021.08.004
[34]	(a) Prajapati, P. K.; Kumar, A.; Jain, S. L. ACS Sustainable Chem. Eng. 2018, 6, 7799. doi: 10.1021/acssuschemeng.8b00755
	(b) Guo, Q.; Xia, S.-G.; Li, X.-B.; Wang, Y.; Liang, F.; Lin, Z.-S; Tung, C.-H.; Wu, L.-Z. Chem. Commun. 2020, 56, 7849. doi: 10.1039/D0CC01091J
	(c) Zhai, G.; Liu, Y.; Lei, L.; Wang, J.; Wang, Z.; Zheng, Z.; Wang, P.; Cheng, H.; Dai, Y.; Huang, B. ACS Catal. 2021, 11, 1988. doi: 10.1021/acscatal.0c05145
	(d) Gong, L.; Sun, J.; Liu, Y.; Yang, G. J. Mater. Chem. A 2021, 9, 21689. doi: 10.1039/D1TA06159C

光催化CO₂参与的σ键断裂羧基化反应研究进展

Recent Advances in Photocatalytic Carboxylation with CO₂ via σ-Bond Cleavage

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 22

References 34

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Qinggang Mei, Qinghan Li. Recent Progress of Visible Light-Induced the Synthesis of C(3) (Hetero)arylthio Indole Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 398-408.
[2]	Yanshuo Zhu, Hongyan Wang, Penghua Shu, Ke'na Zhang, Qilin Wang. Recent Advances on Alkoxy Radicals-Mediated C(sp³)—H Bond Functionalization via 1,5-Hydrogen Atom Transfer [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 1-17.
[3]	Hongqiong Zhao, Miao Yu, Dongxue Song, Qi Jia, Yingjie Liu, Yubin Ji, Ying Xu. Progress on Decarboxylation and Hydroxylation of Carboxylic Acids [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 70-84.
[4]	Yukun Jin, Baoyi Ren, Fushun Liang. Visible Light-Mediated Selective C—F Bond Cleavage of Trifluoromethyl Groups and Its Application in Synthesizing gem-Difluoro-Containing Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 85-110.
[5]	Xiaona Yang, Hongyu Guo, Rong Zhou. Progress in Visible-Light Promoted Transformations of Organosilicon Compounds [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2720-2742.
[6]	Jiaxia Pu, Xiaoying Jia, Lirong Han, Qinghan Li. Research Progress of Visible Light Promoted C—N Bond Fracture to Construct C—C Bond [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2591-2613.
[7]	Lingna Wang, Xiaoqing Liu, Gang Lin, Hongying Jin, Minjun Jiao, Xuefen Liu, Shuping Luo. Photocatalytic Activation of C(sp³)—H Bonds to Form C—S Bonds Catalyzed by (Oxybis(4,1-phenylene))bis(phenylmethanone) [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2848-2854.
[8]	Yu Zhao, Kai Zhang, Yubin Bai, Yantu Zhang, Shihui Shi. A Metal-Free Photocatalytic Hydrosilylation of Alkenes Using Bromide Salt as a Hydrogen Atom Transfer Reagent [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2837-2847.
[9]	Yi Wang, Jian Zhang, Yangzi Liu, Xiaoyan Luo, Weiping Deng. Palladium-Catalyzed Asymmetric [3＋4] Cycloadditions for the Construction of Cyclohepta[b]indoles [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2864-2877.
[10]	Lu Liu, Shuguang Zhang, Renwei Hu, Xiaoxiao Zhao, Jingnan Cui, Weitao Gong. Synthesis and Properties of Phenolic Resin Polymers Based on Pillar[5]arene [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2808-2814.
[11]	Yingjie Liu, Gangqing Shi, Ge Chou, Xin Zhang, Dongxue Song, Ning Chen, Miao Yu, Ying Xu. Progress of α-Position Functionalization of Ethers under Photo/Electrocatalysis [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2664-2681.
[12]	Yaxin Liu, Yu Zhang, Shuping Luo. Design and Synthesis of Thermal Delayed Fluorescence (TADF) Photocatalyst and Its Photocatalytic Dehalogenation Performance [J]. Chinese Journal of Organic Chemistry, 2023, 43(7): 2476-2483.
[13]	Zhongrong Xu, Jieping Wan, Yunyun Liu. Transition Metal-Free C—H Thiocyanation and Selenocyanation Based on Thermochemical, Photocatalytic and Electrochemical Process [J]. Chinese Journal of Organic Chemistry, 2023, 43(7): 2425-2446.
[14]	Ning Chen, Chengdong Zhang, Peng Li, Ge Qiu, Yinjie Liu, Tianlei Zhang. Research Progress in Synthesis of Spirocyclic Compounds Driven by Photo/Electrochemistry [J]. Chinese Journal of Organic Chemistry, 2023, 43(7): 2293-2303.
[15]	Yongzhou Pan, Xiujin Meng, Yingchun Wang, Muxue He. Recent Progress in Electrochemical Fixation of CO₂ to Construct Carboxylic Acid Derivatives [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1416-1434.

光催化CO2参与的σ键断裂羧基化反应研究进展