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Chinese Journal of Organic Chemistry >

2013 , Vol. 33 >Issue 05: 1096 - 1099

DOI: https://doi.org/10.6023/cjoc2012012049

Notes

Access to Cyclohexane-1,2-diol through the Diphenyldiselenide Catalyzed Oxidation of Cyclohexene by Hydrogen Peroxide

  • Yu Lei ,
  • Wang Jun ,
  • Chen Tian ,
  • Ding Kehong ,
  • Pan Yi
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  • a School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;
    b School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002;
    c Jiangsu Yangnong Chemical Engineering Co. Ltd., Yangzhou 225009

Received date: 2012-12-30

  Revised date: 2013-01-16

  Online published: 2013-01-25

Supported by

Project supported by the National Natural Science Fundation of China (No. 21202141), the Priority Academic Program Development of Jiangsu Higher Education Institutions, the Opening Foundation of the Key Laboratory of Environmental Materials and Engineering of Jiangsu Province (Nos. K11024, K090030).

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Abstract

The diphenyldiselenide catalyzed oxidation of cyclohexene by hydrogen peroxide led to cyclohexane-1,2-diol with high conversion and selectivity. Compared with traditional metal catalyst, selenium catalysts are cheaper and less harmful to environment. This synthetic method is also clean and highly atom-economic. Therefore, this reaction is highly applicable.

Key words： selenium; catalysis; green chemistry; cyclohexane-1,2-diol; oxidation

Cite this article

Yu Lei , Wang Jun , Chen Tian , Ding Kehong , Pan Yi . Access to Cyclohexane-1,2-diol through the Diphenyldiselenide Catalyzed Oxidation of Cyclohexene by Hydrogen Peroxide[J]. Chinese Journal of Organic Chemistry, 2013 , 33(05) : 1096 -1099 . DOI: 10.6023/cjoc2012012049

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