Chinese Journal of Organic Chemistry >
Synthesis of Receptors Based on Pyridio[2,3-d]pyrimidines and Their Anion Recognition
Received date: 2013-07-25
Revised date: 2013-10-12
Online published: 2013-10-16
Supported by
Project supported by the Natural Science Fundation of Jiangsu Higher Education Institutions (No. 11KJB150014).
Four new receptors containing pyridio[2,3-d]pyrimidines were synthesized via three-component reaction of 6-aminopyrimidine, substituted benzaldehydes and malononitrile. The properties of the receptors with anions such as F-, Cl-, Br-, AcO-, HSO4- and H2PO4-were examined by UV-Vis spectroscopy. The results showed that receptors have good selectivity to AcO-. However, no obvious changes were observed on the other anions. The Job plot indicated that a 1:1 stoichiometry complex was formed between receptors and anions. The results also showed that hydrogen-bonding interaction was formed between the receptors and anions. The combination assumed above was confirmed by the results of 1H NMR titration.
Huang Zhibin , Liu Xuecheng , Hu Minghua , Lin Wei , Shi Daqing . Synthesis of Receptors Based on Pyridio[2,3-d]pyrimidines and Their Anion Recognition[J]. Chinese Journal of Organic Chemistry, 2014 , 34(2) : 382 -386 . DOI: 10.6023/cjoc201307040
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