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Chinese Journal of Organic Chemistry >

2014 , Vol. 34 >Issue 8: 1487 - 1498

DOI: https://doi.org/10.6023/cjoc201405011

Reviews

Transition-Metal-Catalyzed Arylation of Unactivated C(sp3)—H Bonds Assisted by Bidentate Directing Groups

  • Zhang Bo ,
  • Guan Hanxi ,
  • Liu Bin ,
  • Shi Bingfeng
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  • Department of Chemistry, Zhejiang university, Hangzhou 310007

Received date: 2014-05-07

  Revised date: 2014-05-30

  Online published: 2014-06-11

Supported by

Project supported by the National Natural Science Foundation of China (No. J1210042) and the Fundamental Research Funds for the Central Universities (No. 2014QNA3008).

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Abstract

Recently, transition-metal-catalyzed C—H functionalization has attracted tremendous interest as a valuable tool for carbon-carbon and carbon-heteroatom bond formation. However, due to the inertness of C(sp3)—H bonds and the difficulty to achieving high selectivity among the many chemically similar entities in a given molecule, the selective activation of C(sp3)—H bonds remains a great challenge. The recent progress in transition-metal-catalyzed arylation of unactivated C(sp3)—H bonds assisted by bidentate directing groups is reviewed, including the scope of reactions, mechanism and synthetic applications.

Key words： transition-metal; bidentate directing group; C(sp3)—H activation; arylation

Cite this article

Zhang Bo , Guan Hanxi , Liu Bin , Shi Bingfeng . Transition-Metal-Catalyzed Arylation of Unactivated C(sp3)—H Bonds Assisted by Bidentate Directing Groups[J]. Chinese Journal of Organic Chemistry, 2014 , 34(8) : 1487 -1498 . DOI: 10.6023/cjoc201405011

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